4.7 Article

In situ encapsulation of Pd inside the MCM-41 channel

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 35, Pages 7482-7485

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00300h

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Funding

  1. National Natural Science Foundation of China [21176038]
  2. major State Basic Research Program of China (973 program) [2013CB934000]
  3. major State Basic Research Program of China (863 program) [2013AA030800]

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Pd nanoparticles were successfully introduced into the channels of mesoporous silica MCM-41 with their dispersion well-tuned. We identified the dual role played by CTAB, which was critical for both the micelle template and Pd grafting, leading to the formation of a highly active Pd-MCM-41 nanocomposite for catalysing the Suzuki reaction.

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