4.6 Article

Carbon-slurry optimization for lithium-ion batteries customization

Journal

ELECTROCHIMICA ACTA
Volume 467, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2023.143141

Keywords

Anode slurry; Lithium batteries; Graphite; Discharge capacity; Coulombic efficiency

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This paper investigates the customization of anodes for lithium-ion batteries through the optimization process of carbon-slurry. The study characterizes two commercial graphite active materials and highlights the interference of binder composition on their performance.
The technological application of lithium-ion batteries (LIB) grows constantly, making customization of the batteries a current necessity and sometimes a challenge. In this paper we described carbon-slurry optimization process for anodes of lithium-ion batteries customization by using a surface response statistical experiment with four response variables such specific discharge capacity, coulombic efficiency, anodes mass deviation, and capacity retention. We studied two commercial graphite active materials by characterizing the materials via Raman spectroscopy, SEM, and electrochemical techniques. We corroborate the graphite structure for both materials but with morphological differences such as shape and particle size. The binder composition seems to interfere with the active carbon materials capabilities while it generates better performance for one of them. Although the chemical structure of both materials was confirmed to be the same via Raman experiments, SEM images shows critical morphological differences that interferes with the final slurry thus, affecting the electrochemical performance of the anodes. Further studies are required to understand ECSA and its possible effect on the charge/ discharge capacities of the anodes.

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