Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 73, Pages 13914-13917Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05114b
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Funding
- MINECO of Spain [CTQ2014-51999-P]
- UJI [P11B2014-02]
- FPI program
- MINECO [FPDI-2013-16525]
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The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the tris-NHC-Ag analogue to form the corresponding heteroleptic NHC-MIC silver cage in an unusual reaction involving the simultaneous exchange of the tris-NHC and tris-MIC ligands.
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