Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 86, Pages 15732-15735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06868a
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- CSIR, New Delhi
- DST, New Delhi
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We have designed a unique strategy to obtain a zinc-salen functionalized porous polymer (Zn@SBMMP) with high zinc content (15.3 wt%) by an easy one-step, cost effective and scalable process, which shows unprecedented catalytic efficiency in the CO2 fixation reaction via cycloaddition of CO2 with epoxides. We hypothesize that a high density of Zn-Schiff base/salen units present in the porous polymer network is responsible for the exceptionally high catalytic performance of Zn@SBMMP.
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