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Polymer Science
Z. A. Alrowaili et al.
Summary: The dielectric properties of PVC-fGO films were studied in different temperatures, showing that the high dielectric constant values at low frequencies in different nanocomposites were induced by the space charge effect from electrode polarization. The maximum barrier height decreased with increasing temperature and was independent of the fGo content. The real dielectric modulus decreased with increasing fGO content, while the AC conductivity increased up to 0.3 wt% of fGO and then decreased.
Article
Engineering, Electrical & Electronic
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Summary: Pure and loaded blends of polyvinyl alcohol/carboxymethyl cellulose/polyethylene glycol (PVA/CMC/PEG: 70/15/15%) with zinc sulfide (ZnS) were prepared at different temperatures and characterized. The loaded blends showed decreased optical energy values and a non-monotonic change in refractive index with wavelength. The nonlinear optical parameters reached their maximum values when loaded with ZnS prepared at 300 degrees C. The fluorescence emitted by the blended polymer depended on the temperature of the nanofiller.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
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Polymer Science
Alhulw H. Alshammari et al.
Summary: This paper presents the preparation and characterization of PVC/PVP polymer blend hybrid nanocomposites doped with Er2O3 nanoparticles for optoelectronic applications. The results showed that the addition of Er2O3 nanoparticles had a significant impact on the structural and optical properties of the polymer blend. The polymer nanocomposites exhibited improved dispersion energy, nonlinear refractive index, and optical absorption with the increase in Er2O3 concentration.
Article
Engineering, Electrical & Electronic
A. M. El-Naggar et al.
Summary: This study investigated the impact of Er doping on cation distribution, lattice parameter, crystallite size, and microstrain of single spinel ferrite phase CoFe2-xErxO4 with a cubic structure using Rietveld refinement. The nanofillers integration, miscibility, and surface morphology of PVA/PVP/PEG blended polymer were examined using X-ray diffraction and SEM techniques. Diffuse reflectance data analysis showed a reduction in optical band gap value from 5.14 eV to a value between 4.87 and 5.09 eV depending on the amount of Er in the nanofiller CoFe2-xErxO4. The effect of changing Er content on linear and nonlinear optical parameters and emitted fluorescence colors was discussed, along with the inspection of AC electrical characteristics, dielectric constant, and electric modulus of the blends.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Engineering, Electrical & Electronic
A. M. El-naggar et al.
Summary: Undoped and doped PVA/CMC/PVP polymer blends with ZnS/Co were studied, and the influence of calcination temperature of the nanofiller on the structure and morphology of the blends was explored. The possibility of using the doped blend as UV-blocking materials was examined. The optical and electrical properties of the doped blend at different calcination temperatures were investigated.
OPTICAL AND QUANTUM ELECTRONICS
(2023)
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Materials Science, Multidisciplinary
Zein K. Heiba et al.
Summary: Polyvinyl chloride (PVC)/TiO2/x wt% tetrabutylammonium iodide (TBAI) polymers were prepared and their structure and characteristics were investigated. The loading of TiO2 and TBAI in PVC matrix was examined using various techniques. The impact of TiO2 and TBAI on the surface morphology of PVC was studied through SEM analysis. The potential use of PVC/TiO2/TBAI in UV shielding was explored, and the optical properties and luminescence intensity of the materials were enhanced by the addition of TiO2 and different weight percentages of TBAI.
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A. M. El-naggar et al.
Summary: Polyvinyl alcohol (PVA)/x wt.% polyaniline (PANi) polymer blends were prepared and their properties were investigated. The PANi ratio had an effect on the optical and electrical properties of the blends. The addition of PANi reduced the optical band gap and enhanced the fluorescence intensity of PVA. The dielectric constant, AC electrical conductivity, and activation energy of PVA also varied with PANi content.
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Polymer Science
Alhulw H. Alshammari et al.
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Engineering, Electrical & Electronic
A. M. El-naggar et al.
Summary: Casting and solid-state reaction methods were used to prepare composites of PVA/CMC/PEG/x wt% Zn0.9Cu0.1S (x = 0, 1, 3, 5, 10). The nanofiller Zn0.9Cu0.1S was investigated using XRD Rietveld analysis. Various techniques such as XRD, FTIR, SEM, and EDS were employed to study the structural and morphological changes in the PVA/CMC/PEG blend when loaded with different amounts of Zn0.9Cu0.1S. The filler content (x) had an impact on the linear and nonlinear properties of the host blend, including changes in optical band gaps, fluorescence intensity, emitted colors, and dielectric properties.
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(2023)
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Polymer Science
A. M. El-Naggar et al.
Summary: Doping mixed polymers with appropriate fillers is believed to be the most efficient method to create novel materials for optoelectronic applications. Undoped and doped PVC polymers with ZnS/Mn were fabricated at different temperatures, and their structure and microstructure were analyzed. The distribution of the nanofiller in the PVC matrix was determined using various techniques, and the effect of preparation temperatures on the optical properties of the PVC polymer was studied. Doping with ZnS/Mn decreased the optical band gaps and enhanced fluorescence intensity in the PVC.
Article
Materials Science, Multidisciplinary
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C. Behera et al.
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Ali Badawi et al.
Summary: The study investigated the impact of Fe2O3 NPs on the structural and optical parameters of PVA/G blend, showing that the filling of Fe2O3 NPs can alter the optical properties of the blend. The research found homogeneous distribution of Fe2O3 NPs in the nanocomposite films, as well as the semi-crystalline nature of the NC films.
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M. M. Abdelhamied et al.
Summary: This work utilized a solution cast technique to prepare flexible nanocomposite films of PVA/PANI/Ag with different concentrations of PANI and AgNPs. The samples were characterized by XRD, TEM, and infrared spectroscopy, confirming successful synthesis. Irradiation with oxygen ion beam led to significant improvements in the electrical properties and energy density efficiency of the nanocomposite films.
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Rasheed N. Abed et al.
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Zhenjiang Liu et al.
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Fanghua Luo et al.
Summary: This study developed a self-construction strategy to design and fabricate high thermal conductivity polymer-based composite films with excellent electrical insulation and flexibility. By incorporating a uniform intermediate layer of PVA-CS@MWCNTs, the thermal conductivity of the composite films was significantly improved, while the PVA layers in the sandwich structure maintained the electrical insulation of the films.
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Haifa Mohammed Alghamdi et al.
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Zein K. Heiba et al.
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APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
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Ebtesam M. Alharbi et al.
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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
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Engineering, Electrical & Electronic
A. M. El-naggar et al.
Summary: Nanocomposite PVA/PEG/PVP/SnS2/V films were prepared via thermolysis and casting procedures, and their thermal stability was improved. The effects of doping on optical parameters and emitted colors were investigated. It was found that the nonlinear optical parameters were effectively improved with increasing percentage of SnS2/V dopant.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Materials Science, Multidisciplinary
A. M. El-naggar et al.
Summary: In this study, PVA/CMC/PVP/CdS0.9M0.1 composites were prepared and characterized. Loading CdS0.9M0.1 had a significant impact on the optical parameters and emitted fluorescence features of the PVA/CMC/PVP blend.
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Materials Science, Multidisciplinary
Mai S. Ismail et al.
Summary: This study focused on enhancing optical parameters of PVA polymer by incorporating PbS nanoparticles. Doping PbS nanoparticles can decrease the optical bandgap of PVA films and increase the refractive index values, with the 3% doped sample showing the optimal refractive index value.
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Materials Science, Multidisciplinary
S. Suvarna et al.
Summary: The optical, thermal, crystalline, conductivity and dielectric properties of chlorinated polyethylene/poly (vinyl chloride) (CPE/PVC) blend composites with various loadings of copper alumina (Cu-Al2O3) nanoparticles were investigated in this study. The experiment results showed that the addition of Cu-Al2O3 nanoparticles successfully enhanced the properties of the blend, resulting in improved thermal stability and conductivity.
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Rasheed N. Abed et al.
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Muhammad Aslam et al.
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Tiago B. Tavares et al.
Summary: In this study, composite films composed of PVK and different ferrites were prepared using sonication and drop-casting technique, and their optical and morphological properties were investigated. The introduction of ferrites resulted in increased optical absorption, reduced band gap, broadened emission spectra, and shortened excited state lifetimes of PVK, indicating the creation of donor/acceptor states in the bandgap. Although SEM images showed aggregated ferrites, most of them were well dispersed in the PVK matrix.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
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M. M. Abutalib et al.
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Materials Science, Multidisciplinary
M. T. Elabbasy et al.
Summary: In this study, Chitosan/PVP/Bi2O3 nanocomposite films were synthesized via laser ablation, leading to the breaking of bond chains in Chitosan/PVP, resulting in improved electrical conductivity and antibacterial efficiency. The addition of Bi2O3 NPs at different laser ablation times enhanced the conductive paths among filler particles and increased the number of charge carriers, ultimately improving the conductivity and antibacterial activity of the composite material.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
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Yasmin Khairy et al.
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Alhulw H. Alshammari et al.
Summary: In this study, polymer nanocomposite samples were prepared by the solution casting method with nano-zinc ferrite doping. XRD confirmed the cubic crystal structure of ZnFe2O4 nanoparticles with an average size of 15 nm. The addition of ZnFe2O4 to the polymers blend (PVC/PVP) resulted in different absorption bands in the FTIR spectra. Furthermore, the thermal decomposition stages showed a decrease in activation energy, enthalpy, and Gibbs free energy with increasing zinc ferrite concentration. The dielectric data revealed lower values of dielectric constant with higher ZnFe2O4 content in the polymer, and the AC conductivity increased gradually with frequency while DC conductivity values decreased up to 15.0 wt% zinc ferrite concentration.
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