4.7 Article

Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 54, Pages 10925-10928

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03398e

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Funding

  1. DTRA [HDTRA1-14-1-0014, HDTRA1-10-1-0023]
  2. Deanship of scientific Research (DSR), King Abdulaziz University. Jeddah [23-130-36-HiCi]
  3. DSR

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The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

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