Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 45, Pages 9265-9268Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02585k
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Funding
- Dream Project - Korea Institute of Science and Technology [KIST-2013-2E23996]
- Secondary Battery R&D program of MOTIE/KEIT [10042840]
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The intercalation mechanism of zinc ions into 2 x 2 tunnels of an alpha-MnO2 cathode for rechargeable zinc batteries was revealed. It involves a series of single and two-phase reaction steps and produces buserite, a layered compound with an interlayer spacing of 11 angstrom as a discharge product.
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