Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 77, Pages 14477-14480Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05708f
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- EPSRC
- Engineering and Physical Sciences Research Council [EP/I014519/1] Funding Source: researchfish
- EPSRC [EP/I014519/1] Funding Source: UKRI
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A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.
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