4.7 Article

Amphiphilic hollow porous shell encapsulated Au@Pd bimetal nanoparticles for aerobic oxidation of alcohols in water

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 78, Pages 14601-14604

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05686a

Keywords

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Funding

  1. National Natural Science Foundation of China [21390394]
  2. National Basic Research Program of China [2012CB821700, 2011CB808703]
  3. NSFC [21261130584, 91022030]
  4. 111'' project [B07016]
  5. KAUST [CRG-1-2012-LAI-009]
  6. Ministry of Education, Science and Technology Development Center Project [20120061130012]

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This work describes the design, synthesis and analysis of an amphiphilic hollow mesoporous shell encapsulating catalytically active Au@Pd bimetal nanoparticles. The particles exhibited excellent catalytic activity and stability in the aerobic oxidation of primary and secondary alcohols to their corresponding aldehydes or ketones in water when using air as an oxidizing agent under atmospheric pressure.

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