Single-Component Globular Systems Capable of Plastic or Elastic Deformation and Structural Transitions

Elastic and plastic bending, as well as temperature-induced reversible and irreversible structural transformations, are revealed in single-molecule bicyclic phosphates. These bending properties are rare for globular systems. Structure-property analyses by single-crystal X-ray diffraction and calculations rationalize the observed behaviors. Collectively, this work identifies this class of molecules as promising candidates for flexible ferroelectric materials.

Automated summary

This study reveals the elastic and plastic bending, as well as temperature-induced reversible and irreversible structural transformations, in single-molecule bicyclic phosphates, which are rare in globular systems. The observed behaviors are rationalized through structure-property analyses using single-crystal X-ray diffraction and calculations. Overall, this research identifies this class of molecules as promising candidates for flexible ferroelectric materials.