4.7 Article

A core-shell nanohollow-γ-Fe2O3@graphene hybrid prepared through the Kirkendall process as a high performance anode material for lithium ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 37, Pages 7855-7858

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01195g

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Funding

  1. National Project for EV Batteries (OptimumNano, Shenzhen) [20121110]
  2. Guangdong Innovation Team Project [2013N080]
  3. NSFC [51302007]
  4. Shenzhen Science and Technology Research Grant [ZDSY20130331145131323, CXZZ20120829172325895, JCYJ20120614150338154, JCYJ20130329181509637]

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We synthesized a core-shell structure with graphene as the shell and nano-hollow gamma-Fe2O3 as the core through a Kirkendall process at room temperature. When this hybrid is used as an anode material for lithium-ion batteries, it exhibits a remarkable electrochemical performance: a high reversible capacity of 1095, 833, and 551 mA h g(-1) at the current rates of 0.1 C, 1 C, and 2 C, respectively. When evaluated at 10 C, the capacity can still reach 504 mA h g(-1).

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