4.7 Article

Fine demolition wastes as Supplementary cementitious materials for CO2 reduced cement production

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 392, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2023.131991

Keywords

Demolition waste; Mixed waste; Supplementary Cementitious Materials; Thermal treatment; Hydraulic activity; Pozzolanic activity; Inert filler

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Construction and demolition waste can be potentially used as supplementary cementitious materials in blended cement production, which can reduce CO2 emissions by at least 10.7%. Thermal treatment of waste materials at 500 degrees C improves the mechanical properties of mortars, and pozzolanic ceramic inclusions in waste powders do not affect mortar strength at a 20% substitution rate.
Construction and demolition waste accounts for a significant amount of the total solid waste produced world-wide, and its recycling is challenging. Although some demolition waste is processed into recycled sand and rubble, the finer fractions resulting from screening and washing of recycled aggregates are not used. This research investigates the potential of use of real demolition wastes, namely concrete screening fines (CS), mixed concrete-ceramic screening fines (MS), and mud from recycled aggregates washing (WM), as supplementary cementitious materials (SCMs) in eco-efficient blended cement. The study employed various experimental methods, such as isothermal calorimetry, thermogravimetric analysis (TGA), and setting time tests, to evaluate the hydraulic activity of waste materials and the Chapelle test and TGA to assess their pozzolanic activity. The mechanical properties and microstructure of mortars containing 20% of waste powders were evaluated using compressive strength tests and scanning electron microscopy (SEM). The results showed that thermal treatment of waste materials at 500 degrees C improved the mechanical properties of mortars, increasing Strength Activity Index (SAI) by 10% for CS and MS and by 6% for WM after 90 days of curing. All three waste types achieved similar mechanical properties, with compressive strengths of at least 37.93 MPa, 46.25 MPa, and 51.33 MPa after 7, 28, and 90 days of curing, respectively. The contribution of waste powders to mortar strength was due to filler effect and partially dehydrated C-S-H products. However, pozzolanic ceramic inclusions in waste powders did not affect mortar strength at a 20% substitution rate. Therefore, the research findings indicate that waste materials derived from demolition can potentially be used as environmentally friendly materials in construction. Their use as SCMs with a substitution rate of 20% can reduce the CO2 emissions of cement production by at least 10.7%.

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