Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 41, Pages 8634-8636Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02571k
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- University of Minnesota through the Vince Endowed Chair
- University of Minnesota through the McKnight Endowed Chair
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A formal total synthesis of the cytotoxic natural product lactimidomycin has been achieved in nine steps from (E)-2-methyl-2-pentenoic acid. The 12-membered lactone was efficiently formed via a copper-catalyzed ene-yne coupling/alkyne reduction tandem reaction.
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