4.7 Article

A molecular pulley based on a triply interlocked [2]rotaxane

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 39, Pages 8241-8244

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01301a

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Funding

  1. National Natural Science Foundation of China [21332008, 51373180]
  2. National Basic Research Program [2011CB932501]

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A novel triply interlocked [2]rotaxane based on a triptycene-derived tris(crown ether) host and a guest embedded with three dibenzyl-ammonium and three N-methyltriazolium recognition sites was designed and synthesized, which showed pulley-like shuttling motion controlled by acid and base.

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