Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 38, Pages 8062-8065Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01154j
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Funding
- 973 Program [2012CB821701]
- Ministry of Education of China [IRT1156]
- National Science Fund for Distinguished Young Scholars [20925101]
- National Natural Science Foundation of China [21271125]
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An organic-ligand-free cuprous iodide trinuclear cluster with significant temperature-dependent structural distortion has been synthesized and characterized, which shows thermochromic luminescence originating from a single cluster-centered triplet due to the absence of an organic ligand. This compound also shows interesting reversible temperature dependent phase transition from chiral to centro-symmetric space groups.
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