Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 27, Pages 5864-5867Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00659g
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Funding
- National Science Foundation of China [21173061, 21373070, 21403266, 21303030, 51463002]
- State Key Laboratory of Robotics and System (HIT) [SKLRS-2015-MS-11]
- natural science foundation of Shandong province [ZR2014EMQ001]
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We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.
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