Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 26, Pages 5656-5659Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00231a
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Funding
- National Science Foundation of China [21202129, 21472146]
- Ministry of Science and Technology of PRC (973 program for young scientists) [2014CB548200]
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A non-symmetrical diboron reagent, B(pin)-B(dan), has been utilised in the Pd-catalysed borylation of aryl bromides and chlorides. Remarkably selective formation of aryl-B(dan) bonds is established. This represents a direct and efficient way to introduce masked boronic acids. The synthetic usefulness of this reaction is demonstrated in the preparation of boron-differentiated di- and polyboron compounds.
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