4.7 Article

A hybrid gel-solid-state polymer electrolyte for long-life lithium oxygen batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 39, Pages 8269-8272

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01857a

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Funding

  1. Australian Research Council (ARC) [DP140100401]
  2. Energy efficiency & Resources of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Korea government Ministry of Knowledge Economy [S-2012-10016-00065]

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A hybrid gel-solid-state polymer electrolyte has been used as the separator and an electrolyte for lithium oxygen batteries. It can not only avoid electrolyte evaporation but also protect the lithium metal anode during reactions over long-term cycling. Due to its high ionic conductivity and low activation energy, excellent cycling performance is demonstrated, in which the terminal voltage is higher than 2.2 V after 140 cycles at 0.4 mA cm(-2), with a capacity of 1000 mA h g((composite))(-1).

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