4.6 Article

Stoichiometric Control of Guest Recognition of Self-Assembled Palladium(II)-Based Supramolecular Architectures

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Secondary Bracing Ligands Drive Heteroleptic Cuboctahedral PdII12 Cage Formation

Carles Fuertes Espinosa et al.

Summary: The structural complexity of metal-organic capsules can be increased by incorporating different ligands. A rational design strategy was used to selectively prepare a heteroleptic cage with a large cavity volume. The cage was able to bind multiple polycyclic aromatic hydrocarbon guests simultaneously.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Light-Powered Reversible Guest Release and Uptake from Zn4L4 Capsules

Amit Ghosh et al.

Summary: A strategy for light-powered guest release from a tetrahedral capsule was developed by introducing azobenzene units at its vertices. The tetrahedral capsule containing 12 diazo moieties at its metal-ion vertices was prepared and could undergo isomerization upon ultraviolet irradiation, leading to guest release. Cage re-assembly and guest re-uptake could be achieved by visible-light irradiation. 19F NMR study provided a detailed understanding of how switching led to guest release.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Multidisciplinary

Visible-Light Switching of Metallosupramolecular Assemblies**

Aaron D. W. Kennedy et al.

Summary: A study has shown that a photoswitchable ligand and palladium(II) ions can form dynamic metallosupramolecular structures. By irradiating with light, the distribution of isomers in the ligand can be controlled, resulting in selective disassembly and formation of stable structures. This approach provides a new strategy for reversible control of self-assembled structures.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

Article Chemistry, Multidisciplinary

A Catalogue of Orthogonal Complementary Ligand Pairings for Palladium(II) Complexes

Jason S. Buchanan et al.

Summary: This study reports bis-ligand palladium(II) complexes that exhibit molecular recognition similar to base pairing in DNA. By controlling ligand orientation and denticity, information transfer at the molecular level has been achieved. A reliable and varied set of ligand pairs have been developed, enabling the construction of complex molecular architectures and molecular-level information storage.

CHEMISTRY-AN ASIAN JOURNAL (2022)

Article Chemistry, Multidisciplinary

Software update: The ORCA program system-Version 5.0

Frank Neese

Summary: The latest version 5.0 of the ORCA quantum chemistry program suite represents a significant improvement in performance, numerical robustness, functionality, and user friendliness.

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2022)

Review Chemistry, Multidisciplinary

Roles of Metal Ions in Foldamers and Other Conformationally Flexible Supramolecular Systems

Jess L. Algar et al.

Summary: Conformational control is crucial for molecular function, especially in flexible systems. Metal ions play a significant role in enforcing or modifying secondary structure in foldamers and other conformationally flexible systems. This review explores the influence of metal ions on the spatial positioning of molecules and highlights their potential to achieve various structural outcomes.

ACS ORGANIC & INORGANIC AU (2022)

Review Chemistry, Multidisciplinary

Directing metallo-supramolecular assembly through complementarity

Jess L. Algar et al.

Summary: In chemistry, function and behavior originate directly from structure. In metallosupramolecular self-assembly, strategies are needed to control the formation of highly ordered and well-defined structures.

CHEMICAL COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Discrete Self-Assembled Metallo-Foldamers with Heteroleptic Sequence Specificity

Dan Preston

Summary: This study presents a method for maintaining the accuracy of sequences by using complementary ligand arrangements at the metal center to form discrete and ordered metallo-sequences. These metallo-sequences fold into defined conformations through π-π interactions between electron-rich and -poor aromatic regions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Coordination Cages Selectively Transport Molecular Cargoes Across Liquid Membranes

Bao-Nguyen T. Nguyen et al.

Summary: Chemical purifications require a significant amount of global energy, with coordination cages offering a new technological basis for achieving chemical separation. The selective transport of complex hydrocarbons across liquid membranes enables the isolation of target compounds from mixtures under ambient conditions. By using the selectivities of the cages, a two-stage separation process can isolate a single compound from a mixture of physicochemically similar molecules.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Multidisciplinary

Increasing structural and functional complexity in self-assembled coordination cages

Sonja Pullen et al.

Summary: Progress in metallo-supramolecular chemistry has led to the synthesis of functional nano systems and intelligent materials, with a focus on structures such as helicates, grids, links, knots, spheres, and cages. These assemblies, with nano-scale cavities, offer potential for applications as selective receptors and confined reaction environments. Recent advances include the incorporation of dedicated functionality like catalytic centers and photoswitches, allowing for stimuli control.

CHEMICAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Recognition Properties and Self-assembly of Planar [M(2-pyridyl-1,2,3-triazole)2]2+ Metallo-ligands

Dan Preston et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

Article Chemistry, Multidisciplinary

Self-assembly and Cycling of a Three-state PdxLy Metallosupramolecular System

Dan Preston et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

Article Chemistry, Multidisciplinary

A symmetry interaction approach to [M2L2]4+ metallocycles and their self-catenation

Dan Preston et al.

CHEMICAL COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

High Activity and Efficient Turnover by a Simple, Self-Assembled Artificial Diels-Alderase

Vicente Marti-Centelles et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Construction of Discrete Pentanuclear Platinum(II) Stacks with Extended Metal-Metal Interactions by Using Phosphorescent Platinum(II) Tweezers

Fred Ka-Wai Kong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Reversible C60 Ejection from a Metallocage through the Redox-Dependent Binding of a Competitive Guest

Cedric Colomban et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Article Chemistry, Multidisciplinary

Reversible Guest Uptake/Release by Redox-Controlled Assembly/Disassembly of a Coordination Cage

Vincent Croue et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Supramolecular transformations within discrete coordination-driven supramolecular architectures

Wei Wang et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Inorganic & Nuclear

Double-Decker Coordination Cages

Sreenivasulu Bandi et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Superchiral Pd3L6 Coordination Complex and Its Reversible Structural Conversion into Pd3L3Cl6 Metallocycles

Ondrej Jurcek et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Facile Self-Assembly of Metallo-Supramolecular Ring-in-Ring and Spiderweb Structures Using Multivalent Terpyridine Ligands

Jun-Hao Fu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Chemically and electrochemically induced expansion and contraction of a ferrocene rotor

Synove O. Scottwell et al.

CHEMICAL COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

Timothy R. Cook et al.

CHEMICAL REVIEWS (2015)

Article Chemistry, Multidisciplinary

Homochiral [2]Catenane and Bis[2]catenane from Alleno-Acetylenic Helicates - A Highly Selective Narcissistic Self-Sorting Process

Ori Gidron et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Multidisciplinary Sciences

Multiaddressable molecular rectangles with reversible host-guest interactions: Modulation of pH-controlled guest release and capture

Alan Kwun-Wa Chan et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)

Article Chemistry, Multidisciplinary

Stepwise Halide-Triggered Double and Triple Catenation of Self-Assembled Coordination Cages

Rongmei Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Selective Host-Guest Interactions of a Transformable Coordination Capsule/Tube with Fullerenes

Norifumi Kishi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

One Ligand in Dual Roles: Self-Assembly of a Bis-Rhomboidal-Shaped, Three-Dimensional Molecular Wheel

Xiaocun Lu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

Article Chemistry, Multidisciplinary

Probing a Hidden World of Molecular Self-Assembly: Concentration-Dependent, Three-Dimensional Supramolecular Interconversions

Xiaocun Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Multidisciplinary Sciences

Safe storage of radical initiators within a polyaromatic nanocapsule

Masahiro Yamashina et al.

NATURE COMMUNICATIONS (2014)

Article Chemistry, Multidisciplinary

Light-Triggered Guest Uptake and Release by a Photochromic Coordination Cage

Muxin Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Giant hollow MnL2n spherical complexes: structure, functionalisation and applications

Kate Harris et al.

CHEMICAL COMMUNICATIONS (2013)

Article Chemistry, Multidisciplinary

Template Control over Dimerization and Guest Selectivity of Interpenetrated Coordination Cages

Sabrina Freye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Solid-State Self-Assembly of Triazolylpyridine-Based Helicates and Mesocate: Control of the Metal-Metal Distances

Kristina A. Stevenson et al.

CRYSTAL GROWTH & DESIGN (2012)

Article Chemistry, Multidisciplinary

Anion-Directed Formation and Degradation of an Interlocked Metallohelicate

Ryo Sekiya et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

A solvent-responsive coordination cage

Benan Kilbas et al.

CHEMICAL SCIENCE (2012)

Article Chemistry, Multidisciplinary

Stimuli-responsive Pd2L4 metallosupramolecular cages: towards targeted cisplatin drug delivery

James E. M. Lewis et al.

CHEMICAL SCIENCE (2012)

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Naphthalene Diels-Alder in a Self-Assembled Molecular Flask

Takashi Murase et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Biochemistry & Molecular Biology

The structural basis of allosteric regulation in proteins

Roman A. Laskowski et al.

FEBS LETTERS (2009)

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

Article Multidisciplinary Sciences

White Phosphorus Is Air-Stable Within a Self-Assembled Tetrahedral Capsule

Prasenjit Mal et al.

SCIENCE (2009)

Article Chemistry, Multidisciplinary

The Complex-in-a-Complex cations [(acac)(2)M subset of RU6(p-iPrC(6)H(4)Me)(6)(tpt)(2)(dhbq)(3)](6+): A Trojan horse for cancer cells

Bruno Therrien et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

A short history of SHELX

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2008)

Article Chemistry, Multidisciplinary

Solvato-controlled assembly of Pd3L6 and Pd4L8 coordination boxes

Kosuke Suzuki et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Article Chemistry, Multidisciplinary

Solvent-modulated reversible conversion of a [2 x 2]-grid into a pincerlike complex

Juan Ramirez et al.

CHEMICAL COMMUNICATIONS (2007)

Article Chemistry, Multidisciplinary

Protonmotive force: Development of electrostatic drivers for synthetic molecular motors

James D. Crowley et al.

CHEMISTRY-A EUROPEAN JOURNAL (2006)

Article Chemistry, Inorganic & Nuclear

Self-assembly by ligand-exchange reactions

DK Chand et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2005)

Article Chemistry, Multidisciplinary

Molecular recognition. Self-assembly of molecular trigonal prisms and their host-guest adducts

JD Crowley et al.

CHEMICAL COMMUNICATIONS (2003)

Article Multidisciplinary Sciences

Dynamic chemical devices: Modulation of contraction/extension molecular motion by coupled-ion binding/pH change-induced structural switching

M Barboiu et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2002)