4.6 Article

Ultra-Microporous and Stable MOFs with Zero-Linker Ligands for Gas Capture and Separation

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume -, Issue -, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202301279

Keywords

de-linker; gas separation; MOF; ultra microporosity and stability; zero-linker

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This article highlights the importance of using zero-linker ligands to construct ultra-microporous MOFs with high stability and density, bridging the gap between zeolites and traditional MOFs. Several recently developed ultra-microporous MOFs with zero-linker ligands for gas capture and separation are also highlighted.
Zero-linker ligands have maximized the size coordination efficiency of the metal ions in MOF framework which is important in constructing ultra-microporous MOFs with high stability and density, a bridge between zeolites and traditional MOFs. This article highlighted several recently developed ultra-microporous MOFs with zero-linker ligands for gas capture and separation.

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