Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202302683
Keywords
bis-diazidoborane; boron-doped fused heterocycles; cycloaddition; domino reaction; one-pot construction
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This study reports on the synthesis of a new class of bis-diazidoboranes and their cycloaddition reaction with isonitriles. Complex boron-doped fused heterocycles were constructed in a one-pot process, providing a new strategy for the construction of boron-doped heterocyclic systems.
Boron-doped fused heterocycles have shown great potential in the field of functional materials. This study reports on the synthesis of a new class of bis-diazidoboranes and the discovery of their cycloaddition reaction with isonitriles. Triply fused boron-doped heterocyclic compounds were constructed in a one-pot process through a domino cycloaddition, providing an effective route for constructing complex boron-doped heterocyclic systems. The room temperature domino cyclization reaction of bis-diazidoboranes with isonitriles was reported for the first time. This one-step reaction leads to complex boron-doped fused heterocycles and provides a new strategy for the construction of boron-doped heterocyclic systems.image
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