4.8 Review

Fluoropolymer Nanoparticles Synthesized via Reversible-Deactivation Radical Polymerizations and Their Applications

Related references

Note: Only part of the references are listed.
Review Chemistry, Inorganic & Nuclear

Multifaceted PVDF nanofibers in energy, water and sensors: A contemporary review (2018 to 2022) and future perspective

S. Varun et al.

Summary: In the past decade, there has been a growing interest in polymeric polyvinylidene fluoride (PVDF) nanofibers, particularly in the fields of energy generation (nanogenerators), water treatment (ultra-thin filtration membranes), and sensing technologies (wearable electronics). The enhancement of the 0-phase in PVDF crystals and fibers has been found to improve their electromechanical property, facilitated by the advent of electrospinning technology. PVDF nanofibers also find significant applications in real-time health diagnostics, monitoring, and self-powered bio-implants. This review focuses on the engineering of PVDF material into a suitable crystalline phase and discusses its multifaceted utilization in renewable and sustainable applications.

JOURNAL OF FLUORINE CHEMISTRY (2023)

Article Chemistry, Physical

Recent advances in dispersion and alignment of fillers in PVDF-based composites for high-performance dielectric energy storage

Jing Zhou et al.

Summary: PVDF-based composites play a crucial role in advanced dielectric energy storage due to their exceptional flexibility, high dielectric permittivity, low density, and superior dielectric breakdown strength. The energy storage performance can be significantly enhanced by optimizing the dispersion and alignment of fillers in the PVDF matrix. This review summarizes recent developments in PVDF-based composites for advanced dielectric capacitors, with a focus on the surface modification of fillers to improve their dispersion and the alignment of one-dimensional and two-dimensional fillers to strengthen the dielectric breakdown strength. The challenges and future prospects of PVDF-based composites for advanced dielectric capacitors are also discussed.

MATERIALS TODAY ENERGY (2023)

Review Environmental Sciences

A critical review of the application of polymer of low concern regulatory criteria to fluoropolymers II: Fluoroplastics and fluoroelastomers

Stephen H. Korzeniowski et al.

Summary: Fluoropolymers are a distinct class of high molecular weight polymers with unique properties and functionalities that are essential for products and manufacturing processes. Despite fitting the structural definition of PFAS, fluoropolymers have significant differences in physical, chemical, environmental, and toxicological properties compared to other PFAS. The study demonstrates that fluoropolymers can be considered polymers of low concern and should not be grouped with other PFAS for hazard assessment or regulatory purposes.

INTEGRATED ENVIRONMENTAL ASSESSMENT AND MANAGEMENT (2023)

Article Polymer Science

Preparation and characterization of pH and thermally responsive perfluoropolyether acrylate copolymer micelles and investigation its drug-loading properties

Dezhong Xu et al.

Summary: In this study, a pH and thermally responsive polymer P(PFPHM9-b-DMAEMA-b-PEG-MEA(480)) was prepared and its properties were investigated. The polymer showed pH and temperature sensitivity, with potential application as a drug loading system.

JOURNAL OF APPLIED POLYMER SCIENCE (2023)

Article Chemistry, Inorganic & Nuclear

Fluoropolymers: A special class of per- and polyfluoroalkyl substances (PFASs) essential for our daily life

Bruno Ameduri

Summary: Per- or polyfluoroalkyl substances (PFASs) can be divided into two families: low molar-mass PFASs, which are toxic and restricted, and polymeric ones. Fluoropolymers (FPs) are niche specialty bio-inert and safe polymers with outstanding properties, making them valuable and irreplaceable materials in many high tech applications. Despite the pressure faced by all PFASs, the concerns regarding industrial production of FPs have been addressed, highlighting their separation from conventional PFASs.

JOURNAL OF FLUORINE CHEMISTRY (2023)

Review Polymer Science

Engineering interactions between nanoparticles using polymers

Huibin He et al.

Summary: Nanoparticle assembly is a versatile tool for creating new structural materials with unique properties that go beyond individual nanoparticles. To achieve desired properties and functions, precise control over the interactions between nanoparticle building blocks is necessary. This review summarizes recent advancements in engineering interparticle interactions between nanoparticles, particularly inorganic ones of different sizes, shapes, and compositions, by using structurally defined polymers grafted or absorbed on the nanoparticle surfaces. The discussion focuses on various interactions dominating the assembly, as well as the influence of external fields on polymer-modified nanoparticles.

PROGRESS IN POLYMER SCIENCE (2023)

Article Polymer Science

Dielectric Characterization of Core-Shell Structured Poly(vinylidene fluoride)-grafted-BaTiO3 Nanocomposites

Fatima Ezzahra Bouharras et al.

Summary: The dielectric properties of PVDF-g-BT core-shell structured nanocomposites obtained by RAFT polymerization were investigated. The dielectric constant increased with the addition of BT, exhibiting a larger increase than predicted by usual modeling methods for composite materials, due to the effect of the interfacial core-shell structure. PVDF's known dielectric relaxations were observed in both the neat polymer and its nanocomposites, unaffected by the presence of nanoparticles. A relaxation process due to interfacial polarization was found at higher temperatures, attributed to the high crystallinity of the materials produced by RAFT.

POLYMERS (2023)

Article Chemistry, Multidisciplinary

Main-Chain Fluoropolymers with Alternating Sequence Control via Light-Driven Reversible-Deactivation Copolymerization in Batch and Flow

Kaixuan Chen et al.

Summary: This study achieved controlled synthesis of fluoropolymers for the first time using a novel fluorinated xanthate agent through a light-driven process. The alternating copolymerization of chlorotrifluoroethylene and vinyl esters/amides was successfully carried out under both batch and flow conditions. A two-step photo-flow platform was established to enable in-situ chain-extension for the continuous synthesis of advanced block copolymers from fluoroethylene.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Chemistry, Multidisciplinary

Biological Utility of Fluorinated Compounds: from Materials Design to Molecular Imaging, Therapeutics and Environmental Remediation

Cheng Zhang et al.

Summary: This review discusses the applications of fluorinated molecules in bioengineering and nanotechnology, with a focus on controlling fluorine-fluorine interactions and understanding their impact on biological behavior. The controlled introduction of fluorine and its interactions can provide advantages in imaging, therapeutics, and environmental applications.

CHEMICAL REVIEWS (2022)

Review Chemistry, Multidisciplinary

Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis

Daniel A. Corbin et al.

Summary: The development of photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP) has attracted significant attention due to its ability to produce well-defined polymers under mild reaction conditions using organic photoredox catalysts. However, further investigation is needed to address the limitations of this method and expand its capabilities and applications.

CHEMICAL REVIEWS (2022)

Review Chemistry, Multidisciplinary

Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities

Chenyu Wu et al.

Summary: The use of photocatalysts in controlled polymerization has provided new opportunities for sophisticated macromolecular synthesis. The rational design of photocatalysts based on the knowledge of structure-property-performance relationships allows for rapid and economic tuning of the performance and functionality of polymerization systems, thus advancing polymer science.

CHEMICAL REVIEWS (2022)

Article Polymer Science

Revealing the Molecular-Level Interactions between Cationic Fluorinated Polymer Sorbents and the Major PFAS Pollutant PFOA

Xiao Tan et al.

Summary: This study demonstrates the importance of fluorine-fluorine and electrostatic interactions in the effective sorption of PFOA, a PFAS molecule, from aqueous solutions. Sorbents containing both fluorinated and cationic groups show higher removal efficiency, with electrostatic attraction dominating when the sorbent is highly charged. These findings provide insights for designing novel sorbents for rapid and efficient PFAS removal.

MACROMOLECULES (2022)

Review Chemistry, Multidisciplinary

Computer-Aided Living Polymerization Conducted under Continuous-Flow Conditions†

Zeyu Wang et al.

Summary: Continuous-flow techniques combined with computer science have led to new breakthroughs in synthetic chemistry, including high-throughput living polymerizations and programmable regulations for polymers, advancing the field of polymer engineering with modern techniques.

CHINESE JOURNAL OF CHEMISTRY (2022)

Article Polymer Science

RAFT Polymerization of Semifluorinated Monomers Mediated by a NIR Fluorinated Photocatalyst

Qiankun Ma et al.

Summary: This study presents a strategy for near-infrared (NIR) photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization of semifluorinated monomers using a NIR photocatalyst called fluorophenyl bacteriochlorin. The strategy involves modifying a reduced tetraphenylporphyrin structure with F atoms to enhance the photostability of the photocatalyst. Under NIR light irradiation, the PET-RAFT polymerization exhibits living/control characteristics and temporal modulation. Stable fluorine-containing micelles and fluorinated hydrophobic surfaces are successfully constructed using this strategy.

MACROMOLECULAR RAPID COMMUNICATIONS (2022)

Article Chemistry, Physical

Organocatalyzed Controlled Copolymerization of Perfluorinated Vinyl Ethers and Unconjugated Monomers Driven by Light

Qinzhi Quan et al.

Summary: By developing an organic photoredox catalyst, controlled photo-controlled radical copolymerization of multiple PFVEs and unconjugated comonomers is achieved. This method has high reaction efficiency and can produce a variety of complex fluoropolymers.

ACS CATALYSIS (2022)

Article Chemistry, Multidisciplinary

Hydrolytically Stable Ionic Fluorogels for High-Performance Remediation of Per- and Polyfluoroalkyl Substances (PFAS) from Natural Water

Irene M. Manning et al.

Summary: In this study, a novel polymer network material with a synergistic combination of ionic and fluorous components was reported for the efficient removal of anionic PFAS from water. The material showed significant removal efficiency for 21 legacy and emerging PFAS and could be regenerated for multiple cycles of use.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Polymer Science

Copolymers of vinylidene fluoride with functional comonomers and applications therefrom: Recent developments, challenges and future trends

Bruno Ameduri

Summary: This review presents the radical copolymerization of VDF with M monomer and discusses the properties and applications of the resulting copolymers. It covers the kinetics of copolymerization, control parameters, environmental concerns, and recent research findings.

PROGRESS IN POLYMER SCIENCE (2022)

Article Polymer Science

Interaction of Short-Chain PFAS with Polycationic Gels: How Much Fluorination is Necessary for Efficient Adsorption?

Aditya Choudhary et al.

Summary: In this study, molecular dynamics simulations were used to investigate the adsorption mechanism of GenX, a representative compound for short-chain PFAS, on a polycationic hydrogel with various extents of fluorination in its structure. The simulations showed that the presence of fluorinated segments near cationic groups in the gel structure provides the most efficient adsorption environment for GenX. The electrostatic and hydrophobic interactions offered by the cationic-fluorophilic segments amplify the binding of GenX molecules compared to nonfluorinated cationic or noncationic fluorinated segments.

ACS MACRO LETTERS (2022)

Article Engineering, Environmental

Thermal destruction of PFAS during full-scale reactivation of PFAS-laden granular activated carbon

Rebecca DiStefano et al.

Summary: Granular activated carbon (GAC) is commonly used for removing per and polyfluoroalkyl substances (PFAS) from drinking water and wastewater. This study examined the effectiveness of the reactivation process in destroying PFAS. The results showed that under typical operating conditions, the system achieved full removal of PFAS compounds from GAC and over 99.99% destruction of PFAS compounds through the furnace and abatement system.

REMEDIATION-THE JOURNAL OF ENVIRONMENTAL CLEANUP COSTS TECHNOLOGIES & TECHNIQUES (2022)

Article Chemistry, Multidisciplinary

Organocatalyzed Controlled Radical Copolymerization toward Hybrid Functional Fluoropolymers Driven by Light

Yang Zeng et al.

Summary: In this work, a light-driven organocatalyzed copolymerization method using TFVB was reported for the controlled synthesis of a variety of hybrid fluorine/boron polymers with low dispersities and good chain-end fidelity. The combination of fluorine and boron was shown to provide high-performance copolymer electrolytes with a high lithium-ion transference number, offering new opportunities for engineering high-performance materials for energy storage.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Polymer Science

Fluorine-containing nano-objects with the same compositions but different segment distributions: synthesis, characterization and comparison

Xingpeng Chai et al.

Summary: The study investigates the fluorine-containing nano-objects with different segment distributions but the same compositions. It provides a comprehensive characterization of the synthesized copolymers and nano-objects and demonstrates the significant impact of segment distribution on the hydrophilic/hydrophobic properties of the fluorine-containing nano-objects.

POLYMER CHEMISTRY (2022)

Article Polymer Science

Depolymerizable semi-fluorinated polymers for sustainable functional materials

Devavrat Sathe et al.

Summary: In this study, semi-fluorinated polymers that can undergo chemical recycling at ambient conditions were presented. These polymers possess tunable glass transition temperatures, excellent thermal stability, hydrophobicity, and can be functionalized post-polymerization. These properties make them promising candidates for sustainable functional materials.

POLYMER CHEMISTRY (2022)

Review Polymer Science

Organic-inorganic hybrid nanomaterials prepared via polymerization-induced self-assembly: recent developments and future opportunities

Bing Niu et al.

Summary: Organic-inorganic hybrid nanomaterials are important functional materials prepared through cooperative self-assembly and polymerization-induced self-assembly (PISA). The conventional method of cooperative self-assembly encounters problems with low solids contents and multi-step processes, while PISA enables the preparation of concentrated block copolymer nanomaterials. This review focuses on recent developments in preparing organic-inorganic hybrid nanomaterials via PISA.

POLYMER CHEMISTRY (2022)

Review Polymer Science

Polymer nanoparticles-preparations, applications and future insights: a concise review

Chandan Adhikari

Summary: Polymeric nanoparticles have significant applications in drug delivery, medical diagnostics, and nanomedicine, with recent developments in combining inorganic nanoparticles with polymers for enhanced properties. Their versatility and potential for tunable applications make them highly appealing for various fields of science and engineering.

POLYMER-PLASTICS TECHNOLOGY AND MATERIALS (2021)

Article Chemistry, Multidisciplinary

Design of Polymers for Intracellular Protein and Peptide Delivery

Yiyun Cheng

Summary: The research group focuses on developing polymeric carriers for cytosolic protein delivery, aiming to improve delivery efficiency and bioactivity by modifying polymer structures and introducing different functional groups. The experimental results show that these polymers exhibit excellent performance in delivering tumor antigens, therapeutic peptides, and more in vivo, providing a new approach for future disease treatment.

CHINESE JOURNAL OF CHEMISTRY (2021)

Article Polymer Science

Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization (RDRP)

Zhuo-Ran Zhong et al.

Summary: This study summarizes the challenges and recent achievements in photoflow-RDRP, including droplet/slug flow, mixing techniques, polymerization induced self-assembly, and computer-aided synthesis. It aims to provide informative knowledge for individuals in related fields and stimulate novel ideas to advance polymer synthesis in academia and industry.

CHINESE JOURNAL OF POLYMER SCIENCE (2021)

Article Chemistry, Multidisciplinary

Time-Resolved Small-Angle X-ray Scattering Studies during Aqueous Emulsion Polymerization

Adam Czajka et al.

Summary: The study investigated the aqueous emulsion polymerization of TFEMA using persulfate initiation and monitored the particle size evolution using SAXS and DLS. Well-defined spherical latexes were formed under different conditions, with significant differences observed between surfactant-free and SDS formulations. Comparable polymerization kinetics were observed for in situ SAXS experiments and laboratory-scale syntheses.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Machine-Learning-Guided Discovery of 19F MRI Agents Enabled by Automated Copolymer Synthesis

Marcus Reis et al.

Summary: Modern polymer science faces challenges of multidimensionality, but a computer-guided materials discovery approach, combining automated flow synthesis and machine learning, successfully synthesized 397 unique copolymer compositions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Synthesis of a Stretchable but Superhydrophobic Polymer Thin Film with Conformal Coverage and Optical Transparency

Myung Seok Oh et al.

Summary: A nanoscale ultrathin stretchable polymer film with superhydrophobicity was designed and synthesized using the iCVD method, suitable for waterproof and antifouling surface treatment. The composition of the copolymer film can be adjusted by controlling the flow rates of PFOA and V3D3, achieving the desired superhydrophobic and highly stretchable properties.

CHEMISTRY OF MATERIALS (2021)

Article Biochemistry & Molecular Biology

Thermo- and ROS-Responsive Self-Assembled Polymer Nanoparticle Tracers for 19F MRI Theranostics

Kristyna Kolouchova et al.

Summary: In this study, polymer tracers for F-19 MRI were modified by introducing a redox-responsive monomer, allowing for changes in physicochemical properties in an oxidative environment. These ROS-responsive polymers have potential applications in theranostic purposes, especially in terms of drug delivery systems sensitive to oxidative environments in tumors or inflamed tissues.

BIOMACROMOLECULES (2021)

Article Chemistry, Physical

Designing Weakly Solvating Solid Main-Chain Fluoropolymer Electrolytes: Synergistically Enhancing Stability toward Li Anodes and High-Voltage Cathodes

Mingyu Ma et al.

Summary: By synthesizing a new family of main-chain fluorinated solid polymer electrolytes (MCF-SPEs), the electrochemical window is increased to 5.3 V, significantly reducing dendrite proliferation and enhancing compatibility with various cathodes. Studying the unique solvation structure between MCF-SPEs and Li+ helps elucidate the fundamental effects of fluoropolymers at electrode/electrolyte interfaces.

ACS ENERGY LETTERS (2021)

Review Chemistry, Multidisciplinary

A comparison of RAFT and ATRP methods for controlled radical polymerization

Nghia P. Truong et al.

Summary: RAFT and ATRP are two commonly used controlled radical polymerization methods that can produce functional polymers with specific properties, but they have slightly different mechanisms and applications.

NATURE REVIEWS CHEMISTRY (2021)

Review Polymer Science

Synthetic Routes to Single Chain Polymer Nanoparticles (SCNPs): Current Status and Perspectives

Meshari A. M. Alqarni et al.

Summary: Recent advances in polymer science have made it possible to create single chain polymer nanoparticles (SCNPs) that mimic the folding of natural macromolecules, such as proteins and nucleic acids. However, the synthesis of relatively controlled SCNPs with good folding accuracy remains challenging due to the lack of appropriate chemical synthesis techniques. Despite the development of different types of SCNPs with enhanced properties for various applications, elucidating single chain technology remains crucial.

MACROMOLECULAR RAPID COMMUNICATIONS (2021)

Review Neurosciences

19F Magnetic Resonance Imaging and Spectroscopy in Neuroscience

Michel Modo

Summary: H-1 MRI and multi-nuclear MRI techniques, such as F-19 MRI, allow visualization of brain anatomy, blood flow, and activity, providing rich information. F-19 MRI can also be utilized for visualizing cell migration and treatment. Improvements in F-19 signal detection and introduction of new sensitive probes will enhance the utility of these multi-nuclear studies.

NEUROSCIENCE (2021)

Review Polymer Science

On the Solubility and Stability of Polyvinylidene Fluoride

Jean E. Marshall et al.

Summary: This literature review discusses the solubility and processability of the fluoropolymer polyvinylidine fluoride (PVDF) and its applications in various sectors like construction, automotive engineering, and electronics. The challenges in processing and reusing PVDF due to its limited solubility are also highlighted.

POLYMERS (2021)

Article Chemistry, Multidisciplinary

Visible-Light-Enabled Organocatalyzed Controlled Alternating Terpolymerization of Perfluorinated Vinyl Ethers

Qinzhi Quan et al.

Summary: An organocatalyzed controlled radical alternating terpolymerization of PFVEs and VEs under visible-light irradiation was developed, allowing the synthesis of a broad scope of fluorinated terpolymers with low dispersities and high chain-end fidelity. This method facilitates tuning the chemical compositions by rationally choosing the type and ratio of comonomers, and also enables temporal control of chain-growth and the preparation of novel fluorinated block copolymers. The versatility of this method was showcased by synthesizing fluorinated alternating terpolymers customized to display a variety of desirable properties for solid polymer electrolyte design, leading to new opportunities in high-performance energy storage devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Polymerization-Induced Self-Assembly for the Preparation of Poly(N,N-dimethylacrylamide)-b-Poly(4-tert-butoxystyrene-co-pentafluorostyrene) Particles with Inverse Bicontinuous Phases†

Xin Luo et al.

Summary: Polymerization-induced self-assembly (PISA) is an effective method for preparing block copolymer (BCP) particles with various morphologies, but the preparation of BCPs with inverse bicontinuous phase structure via PISA is rarely reported. In this study, particles with inverse bicontinuous phases were successfully prepared using PISA in ethanol/water. The bicontinuous structure of the BCP particles was characterized by transmission electron microscopy, and the effects of solvent composition and the degree of polymerization of the core-forming block were investigated.

CHINESE JOURNAL OF CHEMISTRY (2021)

Review Polymer Science

Expanding the Scope of Polymerization-Induced Self-Assembly: Recent Advances and New Horizons

Junpeng Cao et al.

Summary: This review discusses the recent advancements in polymerization-induced self-assembly (PISA), highlighting the expansion of methods including synthesis of nonlinear block copolymers, in situ synthesis of polymer blends, and utilization of macro-CTAs with low chain transfer constants. These examples provide new insights into PISA research and demonstrate the potential impact of these methods on polymer and colloid synthesis in the future.

MACROMOLECULAR RAPID COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Machine learning-assisted systematical polymerization planning: case studies on reversible-deactivation radical polymerization

Yu Gu et al.

Summary: The study developed a machine learning-assisted systematic polymerization planning platform that can meet the needs in multiple dimensions such as chemical composition, molecular weight, and molecular weight distribution, and provide optimal reaction conditions to achieve customized polymer targets.

SCIENCE CHINA-CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Principles and Characteristics of Polymerization-Induced Self-Assembly with Various Polymerization Techniques

Erik Jan Cornel et al.

Summary: Polymerization-induced self-assembly (PISA) efficiently combines block copolymer synthesis and nanoparticle formation at high polymer concentrations, enabling the preparation of various nanoparticle morphologies in both polar and nonpolar media. This report discusses the general principles of RAFT-PISA and the nanoparticles generated from this method, as well as outlines PISA formulations that utilize other polymerization methods like ATRP, NMP, ROMP, ROP, etc. Additionally, exotic PISA formulations based on different polymerization methods are emphasized in this review, providing insights into the status and potential of PISA.

CCS CHEMISTRY (2021)

Article Polymer Science

Surfactant-free emulsion polymerization of vinylidene fluoride mediated by RAFT/MADIX reactive poly(ethylene glycol) polymer chains

Mathieu Fuentes-Exposito et al.

Summary: In this study, a robust and straightforward synthesis of surfactant-free poly(vinylidene fluoride) (PVDF) latexes was demonstrated using RAFT/MADIX-mediated emulsion polymerization. Different stabilization modes were carefully examined in VDF emulsion polymerizations conducted in the presence of commercial poly(ethylene glycol) chains (PEG-OH) and those carrying a dithiocarbonate (xanthate) chain end (PEG-X). The use of PEG-X resulted in significantly smaller particle size, indicating a positive effect on particle stabilization compared to PEG-OH.

POLYMER CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Fluoropolymers in biomedical applications: state-of-the-art and future perspectives

Jia Lv et al.

Summary: Fluoropolymers possess unique physicochemical properties and have been widely used in biomedical applications, especially in gene delivery, drug delivery, magnetic resonance imaging, etc. They exhibit distinct mechanisms and features in these specific applications, but also face challenges in utilizing their full potential in the biomedical field.

CHEMICAL SOCIETY REVIEWS (2021)

Review Polymer Science

Non-thermally initiated RAFT polymerization-induced self-assembly

Nankai An et al.

Summary: RAFT PISA enables efficient synthesis of polymeric nanoparticles, but thermal initiation restricts the incorporation of temperature-sensitive biomolecules. Recent developments in non-thermal initiation techniques have addressed this issue, offering new possibilities for bio-related applications.

POLYMER CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Constructing helical nanowires via polymerization-induced self-assembly

Qiumeng Chen et al.

Summary: A new strategy for constructing helical nanowires via polymerization-induced self-assembly (PISA) mediated by a fluorinated stabilizer block has been developed in this work. Ultralong nanowires with helical structure can be readily produced in a wide range of block compositions. The generality of this strategy was well testified by expanding monomer types, showing a morphology transition from spheres to helical nanowires during aging of achiral BCP nano-objects.

RSC ADVANCES (2021)

Article Polymer Science

RAFT polymerisation of trifluoroethylene: the importance of understanding reverse additions

Vincent Bouad et al.

Summary: This article presents the first report on RAFT polymerisation of trifluoroethylene (TrFE), highlighting unique reverse propagation behavior compared to vinylidene fluoride (VDF). By examining the polymerisation process using various spectroscopic and mass spectrometric techniques, relatively well-defined PTrFE with crystalline structure consistent with previous reports was obtained.

POLYMER CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

RAFT-Mediated Polymerization-Induced Self-Assembly

Franck D'Agosto et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

19F Magnetic Resonance Activity-Based Sensing Using Paramagnetic Metals

Da Xie et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Article Chemistry, Multidisciplinary

Low-Fouling Fluoropolymers for Bioconjugation and In Vivo Tracking

Changkui Fu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

A Coordinative Dendrimer Achieves Excellent Efficiency in Cytosolic Protein and Peptide Delivery

Lanfang Ren et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Partially Fluorinated Copolymers as Oxygen Sensitive19F MRI Agents

Nicholas G. Taylor et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Tunable Fluorophobic Effect Determines Nanoparticle Dispersion in Homopolymers and Block Polymers

Zachary M. Marsh et al.

ADVANCED MATERIALS INTERFACES (2020)

Editorial Material Chemistry, Multidisciplinary

Fighting PFAS with PFAS

Rafael Verduzco et al.

ACS CENTRAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Ionic Fluorogels for Remediation of Per- and Polyfluorinated Alkyl Substances from Water

Elango Kumarasamy et al.

ACS CENTRAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Photoorganocatalyzed Divergent Reversible-Deactivation Radical Polymerization towards Linear and Branched Fluoropolymers

Yucheng Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update

Kostas Parkatzidis et al.

Article Chemistry, Multidisciplinary

Surface Diffusion of Dendronized Polymers Correlates with Their Transfection Potential

Jessica A. Kretzmann et al.

LANGMUIR (2020)

Article Engineering, Environmental

Are Fluoropolymers Really of Low Concern for Human and Environmental Health and Separate from Other PFAS?

Rainer Lohmann et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

Article Chemistry, Multidisciplinary

A Cation-Tethered Flowable Polymeric Interface for Enabling Stable Deposition of Metallic Lithium

Zhuojun Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Light-intensity switch enabled nonsynchronous growth of fluorinated raspberry-like nanoparticles

Shantao Han et al.

CHEMICAL SCIENCE (2020)

Article Materials Science, Biomaterials

A fluorinated low-molecular-weight PEI/HIF-1α shRNA polyplex system for hemangioma therapy

Xiaoshuang Guo et al.

BIOMATERIALS SCIENCE (2020)

Article Chemistry, Physical

High-χ alternating copolymers for accessing sub-5 nm domains via simulations

Shanlong Li et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

Review Chemistry, Multidisciplinary

Seeing the Light: Advancing Materials Chemistry through Photopolymerization

Nathaniel Corrigan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Multidisciplinary

Polytetrafluoroethylene: Synthesis and Characterization of the Original Extreme Polymer

Gerard J. Puts et al.

CHEMICAL REVIEWS (2019)

Article Multidisciplinary Sciences

Electroactive materials with tunable response based on block copolymer self-assembly

Ivan Terzic et al.

NATURE COMMUNICATIONS (2019)

Article Multidisciplinary Sciences

Scalable preparation of alternating block copolymer particles with inverse bicontinuous mesophases

Fei Lv et al.

NATURE COMMUNICATIONS (2019)

Article Biochemistry & Molecular Biology

Fluorinated Glycopolymers as Reduction-responsive 19F MRI Agents for Targeted Imaging of Cancer

Changkui Fu et al.

BIOMACROMOLECULES (2019)

Review Nanoscience & Nanotechnology

Designing polymers for advanced battery chemistries

Jeffrey Lopez et al.

NATURE REVIEWS MATERIALS (2019)

Article Chemistry, Physical

Multigeometry Nanoparticles from the Orthogonal Self-Assembly of Block Alternating Copolymers via Simulation

Shanlong Li et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2019)

Review Biochemical Research Methods

Targeted, Stimuli-Responsive, and Theranostic 19F Magnetic Resonance Imaging Probes

Mi Hyeon Cho et al.

BIOCONJUGATE CHEMISTRY (2019)

Article Biochemistry & Molecular Biology

Sensitization of Hypoxic Tumor to Photodynamic Therapy via Oxygen Self-Supply of Fluorinated Photosensitizers

Zhiyong Liu et al.

BIOMACROMOLECULES (2019)

Review Engineering, Biomedical

Polymers for cytosolic protein delivery

Jia Lv et al.

BIOMATERIALS (2019)

Article Biochemistry & Molecular Biology

19F MRI of Polymer Nanogels Aided by Improved Segmental Mobility of Embedded Fluorine Moieties

Oyuntuya Munkhbat et al.

BIOMACROMOLECULES (2019)

Article Chemistry, Multidisciplinary

Self-assembly of Amphiphilic Alternating Copolymers

Qingsong Xu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Review Chemistry, Multidisciplinary

Stimuli-responsive self-assembly of nanoparticles

Marek Grzelczak et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Materials Science, Multidisciplinary

Polymer-based multiferroic nanocomposites via directed block copolymer self-assembly

Ivan Terzic et al.

JOURNAL OF MATERIALS CHEMISTRY C (2019)

Article Nanoscience & Nanotechnology

Fluorine Meets Amine: Reducing Microenvironment-Induced Amino-Activatable Nanoprobes for 19F-Magnetic Resonance Imaging of Biothiols

Pingsheng Huang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Biochemistry & Molecular Biology

Comb-Like Fluorophilic-Lipophilic-Hydrophilic Polymers for Nanocapsules as Ultrasound Contrast Agents

Sophie Houvenagel et al.

BIOMACROMOLECULES (2018)

Article Biochemistry & Molecular Biology

Self-Assembled Thermoresponsive Polymeric Nanogels for F-19 MR Imaging

Kristyna Kolouchova et al.

BIOMACROMOLECULES (2018)

Article Engineering, Biomedical

Dendritic peptide bolaamphiphiles for siRNA delivery to primary adipocytes

Alexander C. Eldredge et al.

BIOMATERIALS (2018)

Article Polymer Science

Semi-Fluorinated Methacrylates: A Class of Versatile Monomers for Polymerization-Induced Self-Assembly

Meng Huo et al.

MACROMOLECULAR RAPID COMMUNICATIONS (2018)

Article Chemistry, Organic

Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

Honghong Gong et al.

SYNLETT (2018)

Article Materials Science, Biomaterials

Oxygen self-sufficient fluorinated polypeptide nanoparticles for NIR imaging-guided enhanced photodynamic therapy

Pan Yuan et al.

JOURNAL OF MATERIALS CHEMISTRY B (2018)

Article Materials Science, Biomaterials

Statistical versus block fluoropolymers in gene delivery

Echuan Tan et al.

JOURNAL OF MATERIALS CHEMISTRY B (2018)

Review Environmental Sciences

A critical review of the application of polymer of low concern and regulatory criteria to fluoropolymers

Barbara J. Henry et al.

INTEGRATED ENVIRONMENTAL ASSESSMENT AND MANAGEMENT (2018)

Article Engineering, Biomedical

Fluoropolymers for intracellular and in vivo protein delivery

Jia Lv et al.

BIOMATERIALS (2018)

Article Chemistry, Multidisciplinary

A degradable fluorinated surfactant for emulsion polymerization of vinylidene fluoride

Sanjib Banerjee et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

Synthetic materials at the forefront of gene delivery

Irene Lostale-Seijo et al.

NATURE REVIEWS CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Organocatalyzed Photocontrolled Radical Polymerization of Semifluorinated (Meth)acrylates Driven by Visible Light

Honghong Gong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Biochemistry & Molecular Biology

Optical and Magnetic Resonance Imaging Using Fluorous Colloidal Nanoparticles

Jaqueline D. Wallat et al.

BIOMACROMOLECULES (2017)

Article Chemistry, Multidisciplinary

β-Cyclodextrin Polymer Network Sequesters Perfluorooctanoic Acid at Environmentally Relevant Concentrations

Leilei Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Light-Mediated Atom Transfer Radical Polymerization of Semi-Fluorinated (Meth)acrylates: Facile Access to Functional Materials

Emre H. Discekici et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Polymer Science

50th Anniversary Perspective: RAFT Polymerization-A User Guide

Sebstien Perrier

MACROMOLECULES (2017)

Review Materials Science, Biomaterials

Nanomaterials engineering for drug delivery: a hybridization approach

M. Rezaa Mohammadi et al.

JOURNAL OF MATERIALS CHEMISTRY B (2017)

Article Chemistry, Multidisciplinary

Photoinitiated Polymerization-Induced Self-Assembly (Photo-PISA): New Insights and Opportunities

Jonathan Yeow et al.

ADVANCED SCIENCE (2017)

Article Biochemistry & Molecular Biology

A Combination of Guanidyl and Phenyl Groups on a Dendrimer Enables Efficient siRNA and DNA Delivery

Hong Chang et al.

BIOMACROMOLECULES (2017)

Article Chemistry, Multidisciplinary

Light-Regulated Polymerization under Near-Infrared/Far-Red Irradiation Catalyzed by Bacteriochlorophyll a

Sivaprakash Shanmugam et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Intramolecular Cross-Linking Methodologies for the Synthesis of Polymer Nanoparticles

Sudheendran Mavila et al.

CHEMICAL REVIEWS (2016)

Review Polymer Science

Single-Chain Folding of Synthetic Polymers: A Critical Update

Ozcan Altintas et al.

MACROMOLECULAR RAPID COMMUNICATIONS (2016)

Article Engineering, Biomedical

Structure-activity relationships of fluorinated dendrimers in DNA and siRNA delivery

Mingming Wang et al.

ACTA BIOMATERIALIA (2016)

Review Pharmacology & Pharmacy

Recent advances of cocktail chemotherapy by combination drug delivery systems

Quanyin Hu et al.

ADVANCED DRUG DELIVERY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Engineering Surfaces through Sequential Stop-Flow Photopatterning

Christian W. Pester et al.

ADVANCED MATERIALS (2016)

Review Biochemistry & Molecular Biology

New photosensitizers for photodynamic therapy

Heidi Abrahamse et al.

BIOCHEMICAL JOURNAL (2016)

Review Chemistry, Multidisciplinary

Photomediated Controlled Radical Polymerization and Block Copolymerization of Vinylidene Fluoride

Alexandru D. Asandei

CHEMICAL REVIEWS (2016)

Review Chemistry, Multidisciplinary

Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications

Mao Chen et al.

CHEMICAL REVIEWS (2016)

Article Chemistry, Multidisciplinary

Nanotechnology for protein delivery: Overview and perspectives

Mikyung Yu et al.

JOURNAL OF CONTROLLED RELEASE (2016)

Article Chemistry, Inorganic & Nuclear

Syntheses and morphologies of fluorinated diblock copolymer prepared via RAFT polymerization

Bishnu P. Koiry et al.

JOURNAL OF FLUORINE CHEMISTRY (2016)

Article Polymer Science

A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self Assembly

Sarah L. Canning et al.

MACROMOLECULES (2016)

Review Polymer Science

Photomediated controlled radical polymerization

Xiangcheng Pan et al.

PROGRESS IN POLYMER SCIENCE (2016)

Article Polymer Science

Enhancing Photodynamic Therapy Efficacy by Using Fluorinated Nanoplatform

Yurong Que et al.

ACS MACRO LETTERS (2016)

Article Materials Science, Biomaterials

Screening of efficient polymers for siRNA delivery in a library of hydrophobically modified polyethyleneimines

Wanwan Shen et al.

JOURNAL OF MATERIALS CHEMISTRY B (2016)

Article Multidisciplinary Sciences

Perfluorocyclobutyl Aryl Ether-Based ABC Amphiphilic Triblock Copolymer

Binbin Xu et al.

SCIENTIFIC REPORTS (2016)

Review Chemistry, Multidisciplinary

Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions

Marc Pera-Titus et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Self-Assembled Fluorodendrimers Combine the Features of Lipid and Polymeric Vectors in Gene Delivery

Hui Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Multidisciplinary

Surface-Engineered Dendrimers in Gene Delivery

Jiepin Yang et al.

CHEMICAL REVIEWS (2015)

Article Environmental Sciences

Perfluoroalkyl and polyfluoroalkyl substances in consumer products

Matthias Kotthoff et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2015)

Article Polymer Science

Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons

Megan R. Hill et al.

MACROMOLECULES (2015)

Article Physics, Multidisciplinary

Mechanical behaviour of nanoparticles: Elasticity and plastic deformation mechanisms

Celine Gerard et al.

PRAMANA-JOURNAL OF PHYSICS (2015)

Review Pharmacology & Pharmacy

Evolution of contrast agents for ultrasound imaging and ultrasound-mediated drug delivery

Vera Paefgen et al.

FRONTIERS IN PHARMACOLOGY (2015)

Review Chemistry, Multidisciplinary

Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials

Zonglin Chu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Multidisciplinary

Electrochemistry of Nanoparticles

Steven E. F. Kleijn et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Biochemistry & Molecular Biology

Size-Dependent Knockdown Potential of siRNA-Loaded Cationic Nanohydrogel Particles

Lutz Nuhn et al.

BIOMACROMOLECULES (2014)

Review Chemistry, Multidisciplinary

(Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applications

Frederic Boschet et al.

CHEMICAL REVIEWS (2014)

Review Chemistry, Multidisciplinary

Cationic Polymer Nanoparticles and Nanogels: From Synthesis to Biotechnological Applications

Jose Ramos et al.

CHEMICAL REVIEWS (2014)

Review Chemistry, Multidisciplinary

Polymer-encapsulated organic nanoparticles for fluorescence and photoacoustic imaging

Kai Li et al.

CHEMICAL SOCIETY REVIEWS (2014)

Review Physics, Applied

Mechanical properties of nanoparticles: basics and applications

Dan Guo et al.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2014)

Article Chemistry, Multidisciplinary

Multimodal Polymer Nanoparticles with Combined 19F Magnetic Resonance and Optical Detection for Tunable, Targeted, Multimodal Imaging in Vivo

Barbara E. Rolfe et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Fluorous Microgel Star Polymers: Selective Recognition and Separation of Polyfluorinated Surfactants and Compounds in Water

Yuta Koda et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Macromolecular Engineering by Atom Transfer Radical Polymerization

Krzysztof Matyjaszewski et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance

Jiangtao Xu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Nanoscale Metal-Organic Framework for Highly Effective Photodynamic Therapy of Resistant Head and Neck Cancer

Kuangda Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Polymer Science

Fluorinated poly(meth)acrylate: Synthesis and properties

Wenqiang Yao et al.

POLYMER (2014)

Article Polymer Science

Synthesis of a multimodal molecular imaging probe based on a hyperbranched polymer architecture

Nathan R. B. Boase et al.

POLYMER CHEMISTRY (2014)

Review Polymer Science

Recent progress in fluoropolymers for membranes

Zhaoliang Cui et al.

PROGRESS IN POLYMER SCIENCE (2014)

Review Polymer Science

Nitroxide-mediated polymerization

Julien Nicolas et al.

PROGRESS IN POLYMER SCIENCE (2013)

Article Chemistry, Multidisciplinary

Cationic Nanohydrogel Particles as Potential siRNA Carriers for Cellular Delivery

Lutz Nuhn et al.

ACS NANO (2012)

Review Chemistry, Multidisciplinary

The fluorous effect in biomolecular applications

Massimo Cametti et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Polymer Science

Mesogen-Driven Formation of Triblock Copolymer Cylindrical Micelles

Yang Gao et al.

MACROMOLECULES (2012)

Article Polymer Science

RAFT Agent Design and Synthesis

Daniel J. Keddie et al.

MACROMOLECULES (2012)

Review Nanoscience & Nanotechnology

Nanoparticles: a boon to drug delivery, therapeutics, diagnostics and imaging

Suphiya Parveen et al.

NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE (2012)

News Item Chemistry, Physical

POLYMERS FOR GENE DELIVERY Charged for success

Enrico Mastrobattista et al.

NATURE MATERIALS (2012)

Proceedings Paper Chemistry, Multidisciplinary

Study on Emulsion Polymerization of Fluorinated Acrylate and its Application

Dan Fan et al.

ADVANCES IN ENVIRONMENTAL SCIENCE AND ENGINEERING, PTS 1-6 (2012)

Review Chemistry, Multidisciplinary

Tailoring nanocarriers for intracellular protein delivery

Zhen Gu et al.

CHEMICAL SOCIETY REVIEWS (2011)

Article Engineering, Environmental

Polyfluorinated Compounds: Past, Present, and Future

Andrew B. Lindstrom et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2011)

Review Polymer Science

Polymer nanoparticles: Preparation techniques and size-control parameters

J. Prasad Rao et al.

PROGRESS IN POLYMER SCIENCE (2011)

Article Chemistry, Multidisciplinary

One-Pot Synthesis of Biomimetic Shell Cross-Linked Micelles and Nanocages by ATRP in Alcohol/Water Mixtures

Shinji Sugihara et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Review Chemistry, Multidisciplinary

Activatable Photosensitizers for Imaging and Therapy

Jonathan F. Lovell et al.

CHEMICAL REVIEWS (2010)

Review Chemistry, Medicinal

Delivery of Therapeutic Proteins

Dipak S. Pisal et al.

JOURNAL OF PHARMACEUTICAL SCIENCES (2010)

Article Chemistry, Multidisciplinary

Functional Hyperbranched Polymers: Toward Targeted in Vivo 19F Magnetic Resonance Imaging Using Designed Macromolecules

Kristofer J. Thurecht et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Polymer Science

Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process

Ryan C. Hayward et al.

MACROMOLECULES (2010)

Article Chemistry, Physical

Fluorinated microemulsions as reaction media for fluorous nanoparticles

Martin J. Hollamby et al.

SOFT MATTER (2010)

Review Chemistry, Physical

End-Grafted Polymer Chains onto Inorganic Nano-Objects

Demetra S. Achilleos et al.

MATERIALS (2010)

Article Polymer Science

Iodine Transfer Copolymerization of Vinylidene Fluoride and α-Trifluoromethacrylic Acid in Emulsion Process without Any Surfactants

Cyrille Boyer et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2009)

Article Polymer Science

Fluorous Miniemulsions: A Powerful Tool to Control Morphology in Metallocene-Catalyzed Propene Polymerization

Svetlin Nenov et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2009)

Review Chemistry, Multidisciplinary

Toward living radical polymerization

Graeme Moad et al.

ACCOUNTS OF CHEMICAL RESEARCH (2008)

Article Biochemical Research Methods

19F- and Fluorescently Labeled Micelles as Nanoscopic Assemblies for Chemotherapeutic Delivery

Wenjun Du et al.

BIOCONJUGATE CHEMISTRY (2008)

Article Biochemistry & Molecular Biology

Amphiphilic Hyperbranched Fluoropolymers as Nanoscopic 19F Magnetic Resonance Imaging Agent Assemblies

Wenjun Du et al.

BIOMACROMOLECULES (2008)

Article Polymer Science

Atom transfer radical dispersion polymerization in an ethanol/water mixture

Wen-Ming Wan et al.

MACROMOLECULES (2007)

Letter Chemistry, Multidisciplinary

Definition of superhydrophobic states

Shutao Wang et al.

ADVANCED MATERIALS (2007)

Review Polymer Science

Polymeric protein delivery systems

Kuen Yong Lee et al.

PROGRESS IN POLYMER SCIENCE (2007)

Article Polymer Science

Controlled synthesis of carboxylic acid end-capped poly(heptadecafluorodecyl acrylate) and copolymers with 2-hydroxyethyl acrylate

Bruno Grignard et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2007)

Review Polymer Science

Controlled/living radical polymerization: Features, developments, and perspectives

Wade A. Braunecker et al.

PROGRESS IN POLYMER SCIENCE (2007)

Article Polymer Science

Synthesis of fluorinated diblock copolymer by ATRP and its application of PAVAc polymerization in ScCO2

Yajun Yang et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2006)

Review Chemistry, Multidisciplinary

Use of iodocompounds in radical polymerization

Ghislain David et al.

CHEMICAL REVIEWS (2006)

Review Engineering, Biomedical

Parameters influencing the stealthiness of colloidal drug delivery systems

Arnaud Vonarbourg et al.

BIOMATERIALS (2006)

Article Multidisciplinary Sciences

A dielectric polymer with high electric energy density and fast discharge speed

Baojin Chu et al.

SCIENCE (2006)

Review Oncology

Photodynamic therapy and anti-tumour immunity

Ana P. Castano et al.

NATURE REVIEWS CANCER (2006)

Article Chemistry, Multidisciplinary

Simultaneous, segregated storage of two agents in a multicompartment micelle

TP Lodge et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Review Polymer Science

Macromolecular design via reversible addition-fragmentation chain transfer (RAFT)/Xanthates (MADIX) polymerization

S Perrier et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2005)

Article Polymer Science

RAFT polymerization of pentafluorophenyl methacrylate:: Preparation of reactive linear diblock copolymer

M Eberhardt et al.

MACROMOLECULAR RAPID COMMUNICATIONS (2005)

Review Chemistry, Physical

Nanostructured materials for advanced energy conversion and storage devices

AS Aricò et al.

NATURE MATERIALS (2005)

Review Environmental Sciences

Synthesis of environmentally relevant fluorinated surfactants - a review

HJ Lehmler

CHEMOSPHERE (2005)

Review Pharmacology & Pharmacy

Distribution, functionality and gene regulation of folate receptor isoforms: implications in targeted therapy

H Elnakat et al.

ADVANCED DRUG DELIVERY REVIEWS (2004)

Article Multidisciplinary Sciences

Multicompartment micelles from ABC miktoarm stars in water

ZB Li et al.

SCIENCE (2004)

Review Chemistry, Inorganic & Nuclear

Novel self-assembled molecular aggregates formed by fluoroalkyl end-capped oligomers and their application

H Sawada

JOURNAL OF FLUORINE CHEMISTRY (2003)

Review Chemistry, Multidisciplinary

New polymer synthesis by nitroxide mediated living radical polymerizations

CJ Hawker et al.

CHEMICAL REVIEWS (2001)

Review Chemistry, Multidisciplinary

Atom transfer radical polymerization

K Matyjaszewski et al.

CHEMICAL REVIEWS (2001)

Review Radiology, Nuclear Medicine & Medical Imaging

MR imaging of the breast for the detection, diagnosis, and staging of breast cancer

SG Orel et al.

RADIOLOGY (2001)

Review Pharmacology & Pharmacy

Fluorocarbons and fluorinated amphiphiles in drug delivery and biomedical research

MP Krafft

ADVANCED DRUG DELIVERY REVIEWS (2001)