Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 1, Pages 54-57Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08203f
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Funding
- Shanghai Rising-Star Program [14QA1400500]
- National Basic Research Program of China (973 Program) [2012CB720300]
- National Nature Science Foundation of China [21274023, 21102016, 21102157]
- Shanghai Scientific and Technological Innovation Project [13520711500]
- Development and Innovation of Instrument Functions, CAS [Y27YQ1110G]
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We report herein a visible light induced generation of a carbanion via double-SET and its application in cyclopropanation of alkenes. This new synthetic approach to form cyclopropane derivatives was conducted under mild conditions, using sunlight in open air, showing the features such as environmental benignness and an easy to handle procedure.
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