4.6 Review

Recent Progress on the Synthesis and Modified Strategies of Zeolitic-Imidazole Framework-67 Towards Electrocatalytic Oxygen Evolution Reaction

Related references

Note: Only part of the references are listed.
Article Materials Science, Multidisciplinary

In situ insight into the low-temperature promotion of ZIF-67 in electrocatalytic oxygen evolution reaction

Anna G. Dymerska et al.

Summary: An efficient electrocatalyst for sustainable hydrogen-fuel production was designed by fabricating cobalt oxyhydroxide catalysts through low-temperature calcination of ZIF-67. The treated ZIF-67 at 200 degrees C exhibited the most electroactive composition with a high electrochemically active surface and turnover frequency, resulting in a robust catalyst for improved electrochemical energy conversion from water. In situ spectroscopy and microscopic techniques revealed the active intermediates and proposed the lattice oxygen mechanism of the reaction.

MATERIALS & DESIGN (2023)

Article Chemistry, Physical

Solvent-Free Mechanochemical Preparation of Metal-Organic Framework ZIF-67 Impregnated by Pt Nanoparticles for Water Purification

Mahya Afkhami-Ardekani et al.

Summary: In this study, ZIF-67, a crystalline metal-organic framework (MOF), was synthesized using the solvent-free ball milling method. Platinum metal ions were loaded in the MOF cavities through impregnation. The prepared Pt@ZIF-67 compound was characterized using various methods, and the results showed that Pt nanoparticles were located inside the pores of ZIF-67. Pt@ZIF-67 exhibited high catalytic efficiency in the reduction of nitrophenol compounds in water.

CATALYSTS (2023)

Article Chemistry, Physical

Metal-organic framework derived core-shell nanoparticles as high performance bifunctional electrocatalysts for HER and OER

Kinjal B. Patel et al.

Summary: This research develops an efficient bifunctional electrocatalyst for both hydrogen and oxygen reactions. Through simple pyrolysis of a nickel-based metal organic framework at temperatures of 600, 700, and 800 ℃, three bifunctional electrocatalysts, Ni@NCS-600, Ni@NCS-700, and Ni@NCS-800, were prepared. Among them, Ni@NCS-800 exhibits extremely low overpotential and shows high catalytic activity comparable to precious state-of-the-art catalysts (RuO2 and Pt/C).

APPLIED SURFACE SCIENCE (2023)

Article Electrochemistry

Pd encapsulated core-shell ZIF-8/ZIF-67 for efficient oxygen evolution reaction

Sagar Varangane et al.

Summary: The tailored core-shell ZIF-8/ZIF-67 nanostructures with encapsulated Pd exhibit efficient electrocatalytic oxygen evolution reaction (OER) with low Tafel slope and overpotential, demonstrating excellent charge mobility and durability.

ELECTROCHIMICA ACTA (2023)

Article Chemistry, Inorganic & Nuclear

Gas-solid phase flow synthesis of the ZIF-67 for efficient electrochemical oxygen evolution and mechanism

Jun Zhao et al.

Summary: In this study, the classical ZIF-67 was successfully synthesized using a gas-solid phase two-phase flow method. Kinetic analysis of the reaction mechanism was conducted by detecting the P-XRD patterns of products at different reaction times. The single crystal ZIF-67 exhibited good activity for oxygen evolution reactions at a current density of 10 mA/cm2 in a 1 mol/L KOH solution. Density functional theory calculations suggested that post-formed Co centers during the OER process were responsible for the high activity. This study provides a new approach for the bulk preparation of highly active center electrocatalysts using novel gas-solid phase synthesis reactions.

INORGANIC CHEMISTRY COMMUNICATIONS (2023)

Article Chemistry, Physical

Construction of ZIF-67/MIL-88(Fe, Ni) catalysts as a novel platform for efficient overall water splitting

Pinghua Chen et al.

Summary: A novel hybrid nanostructure of ZIF-67/MIL-88(Fe, Ni) named Co-M-Fe/Ni(x) was synthesized and exhibited highly efficient and stable bifunctional catalytic performance for both oxygen and hydrogen evolution reactions in alkaline electrolyte. The Co-M-Fe/Ni(150) showed excellent performance for overall water splitting with low overpotential values and achieved a low potential of 1.52 V @ 10 mA cm-2.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Chemistry, Physical

Bifunctional zeolitic imidazolate framework-67 coupling with CoNiSe electrocatalyst for efficient hydrazine-assisted water splitting

Wentao Liu et al.

Summary: By employing hydrazine oxidation reaction (HzOR) instead of oxygen evolution reaction (OER), energy-saving hydrogen generation can be realized. Here, a combined experimental and theoretical investigation of zeolitic imidazolate framework-67 coupling with CoNiSe-3 (ZIF67@CoNiSe-3) as an efficient electrocatalyst towards both hydrogen evolution reaction (HER) and HzOR is introduced. The as-prepared ZIF67@CoNiSe-3 with nanoflower structure and highly porous ultrathin nanosheet arrays endow advanced electrocatalytic properties for HER and HzOR.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Review Chemistry, Physical

Advanced MOF-based electrode materials for supercapacitors and electrocatalytic oxygen reduction

Bolong Yang et al.

Summary: Metal-organic frameworks (MOFs) have gained significant attention for their diverse structures, favorable porous properties, and tunable chemical compositions. In the field of electrochemical energy storage and conversion, MOF-based materials play a crucial role due to their ability to regulate chemical composition at the molecular level and their highly porous frameworks for facilitating mass and charge transfer. This review discusses the strategies for designing targeted MOF-based materials and their potential applications in supercapacitors and electrocatalytic oxygen reduction reaction (ORR).

NANO RESEARCH (2023)

Article Electrochemistry

Controlled synthesis of MOF-derived hollow and yolk-shell nanocages for improved water oxidation and selective ethylene glycol reformation

Minghong Huang et al.

Summary: In this work, novel nanostructured electrocatalysts are developed through an etching-doping reconstruction strategy from a Co-based MOF precursor. These electrocatalysts exhibit outstanding performance in the oxygen evolution reaction and the oxidation of small organic molecules.

ESCIENCE (2023)

Review Chemistry, Multidisciplinary

Critical Review, Recent Updates on Zeolitic Imidazolate Framework-67 (ZIF-67) and Its Derivatives for Electrochemical Water Splitting

Harsharaj S. Jadhav et al.

Summary: Designing and constructing low-cost electrocatalysts with high activity and stability is challenging. This review focuses on metal-organic frameworks (MOFs) as precursor materials for efficient electrocatalysis. Different synthesis approaches and strategies to enhance activity and stability are discussed. The review also provides insights into the applications of MOFs in oxygen and hydrogen evolution reactions and overall water splitting.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

A synergy establishment by metal-organic framework and carbon quantum dots to enhance electrochemical water oxidation

Qiuxiang Mou et al.

Summary: By introducing carbon quantum dots (CQDs) into porous NiFe-MOF, a composite porous structure CQDs(10)@NiFe-MOF-A was fabricated. The incorporation of CQDs improved the electrical conductivity of the material, and the regulation of the electronic structure of metal active sites resulted in outstanding performance of the catalyst in oxygen evolution reaction (OER).

CHINESE CHEMICAL LETTERS (2022)

Article Chemistry, Physical

Fabricating a Functionalized Polyoxometalate with ZIF-8: AComposite Material for Water Oxidation in a Wide pH Range

Sateesh Mulkapuri et al.

Summary: An efficient electrocatalyst for water oxidation has been synthesized in this study, and its electrochemical properties have been extensively investigated. By encapsulating a functionalized Keggin polyoxometalate (POM) anion into a zeolitic-type framework material, a host-guest-type composite material was obtained, which exhibits excellent water oxidation performance over a wide pH range.

CHEMISTRY OF MATERIALS (2022)

Article Energy & Fuels

Facile synthesis of zeolitic imidazolate framework-67/vanadium-doped nickel hydroxide as active electrocatalyst for oxygen evolution reaction

Kamakshaiah Charyulu Devarayapalli et al.

Summary: In this study, a nanostructure composed of zeolitic imidazolate framework and vanadium-doped nickel hydroxide was proposed as a highly efficient and stable electrocatalyst for water splitting. The resulting nanostructure exhibited enhanced electrocatalytic activity, surface area, and pore volume, and demonstrated excellent performance in alkaline water electrolysis.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Article Chemistry, Physical

Electrocatalyst nanoarchitectonics with molybdenum-cobalt bimetallic alloy encapsulated in nitrogen-doped carbon for water splitting reaction

Riyue Ge et al.

Summary: A series of cobalt-molybdenum alloy nanorods encapsulated in N-doped carbon shells (CoMo@NC) were synthesized via carbonization-reduction method. The optimized catalyst exhibited excellent catalytic performances for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline solution, as well as high durability. Pyridinic-N atoms of graphene anchored on CoMo alloy nanoparticles effectively modulated the electronic structure to generate optimal free energy of hydrogen adsorption.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Trimetallic CoNiFe-layered double hydroxides: Electronic coupling effect and oxygen vacancy for boosting water splitting

Jing Yao et al.

Summary: This study presents the fabrication of a trimetallic CoNiFe-layered double hydroxide (LDH) catalyst with optimized intrinsic activity. The catalyst shows low overpotentials for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), demonstrating superior performance compared to other LDH catalysts. The development of this trimetallic LDH catalyst holds great potential in hydrogen production.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Inorganic & Nuclear

Construction of ZIF-67-On-UiO-66 Catalysts as a Platform for Efficient Overall Water Splitting br

Pinghua Chen et al.

Summary: In this study, a novel hybrid nanostructure of metal-organic frameworks (MOFs) was successfully prepared and showed highly efficient and stable bifunctionality of both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in an alkaline medium. The mechanism behind its superior electrocatalytic performance was discussed based on experimental results.

INORGANIC CHEMISTRY (2022)

Article Materials Science, Multidisciplinary

Cobalt-nickel layered double hydroxide on hollow Co3S4/CuS derived from ZIF-67 for efficient overall water splitting

Ge Li et al.

Summary: In this study, a novel hollow Co3S4/CuS@CoNi-LDH nanocomposite was designed and applied in electrochemical water splitting. The results demonstrate that this nanocomposite exhibits efficient oxygen evolution reaction and hydrogen evolution reaction. Furthermore, the water splitting device assembled with the nanocomposite as both anode and cathode requires low potential for achieving high efficiency overall water splitting.

MATERIALS RESEARCH LETTERS (2022)

Article Green & Sustainable Science & Technology

Metal-organic frameworks-derived nitrogen-doped carbon with anchored dual-phased phosphides as efficient electrocatalyst for overall water splitting

Jiancheng Li et al.

Summary: The development of efficient catalysts is essential for utilizing green energy in clean electrochemical energy conversion systems. In this study, cobalt phosphides nanorods anchored in N-doped carbon nanosheets were synthesized through a cation-induced strategy. The optimized Co2P/CoP-NC nanomaterial exhibited high catalytic activity for both the HER and OER in alkaline media, as well as considerable durability.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2022)

Article Nanoscience & Nanotechnology

Effective Formation of a Mn-ZIF-67 Nanofibrous Network via Electrospinning: An Active Electrocatalyst for OER in Alkaline Medium

Sam Sankar Selvasundarasekar et al.

Summary: In this study, a bimetallic ZIF system was constructed and nanofibers were obtained using electrospinning technique. The active center for electrocatalytic oxygen evolution reaction was identified as Mn3+ in the Mn-incorporated ZIF-67 nanofibers, with Co2+ ions suppressing the Jahn-Teller distortion. The obtained nanofibers showed promising electrocatalytic performance with low overpotential and high current density.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Physical

Metal-organic framework (MOF) composites as promising materials for energy storage applications

Yi Peng et al.

Summary: Metal-organic framework (MOF) composites are considered important energy storage materials due to their high porousness, multifunction, various structures, and controllable chemical compositions, but they still face challenges and difficulties in batteries and supercapacitors.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

Article Energy & Fuels

Trace of transition metal dopants induced charge redistribution on the MOF-derived CoP/NC electrocatalysts to improve water-splitting efficiency

Mingjie Sun et al.

Summary: In this study, trace transition metals were used as dopants to optimize the intermediate adsorption/desorption of CoP catalysts. The introduction of trace heteroatoms modulated the electronic configuration of Co and P, leading to improved catalytic activity and stability for electrochemical water splitting. The obtained Ni-CoP-2 catalyst exhibited low overpotentials and achieved high current densities in both acidic and alkaline electrolytes.

APPLIED ENERGY (2022)

Article Engineering, Environmental

Hollow nanopompoms engineered via a weak-strong coetching strategy for high-performance electrocatalysts

Shunli Li et al.

Summary: This study achieved structural transitions of metal-organic frameworks through a weak-strong competitive coordination strategy to prepare high-performance electrocatalysts, which is of great significance for metal-air batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Inorganic & Nuclear

A systematic review on recent advances of metal-organic frameworks-based nanomaterials for electrochemical energy storage and conversion

Suhail Mubarak et al.

Summary: The development of environmentally friendly and cost-effective energy storage and conversion technologies is of great importance in combating pollution and addressing the imminent energy problem. Metal-organic frameworks (MOFs) have been extensively used as precursors for the production of carbon resources, metal-metal composites, and their combinations with variable and governable nanoscale structures and elemental configurations for electrochemical energy applications. However, the poor electrical conductivity and constricted nanopores of MOFs have been addressed through the combination with diverse efficient components.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Design and syntheses of hybrid zeolitic imidazolate frameworks

Yupeng Han et al.

Summary: Zeolitic imidazolate frameworks (ZIFs) have been developed to mimic the structural characteristics of zeolites, with high surface area and adjustable pore size being their main features. The emerging hybrid zeolitic imidazolate frameworks (HZIFs) combine the advantages of zeolites and ZIFs, such as high stability and porosity. HZIFs find wide applications in electrocatalysis, photocatalysis, and ion storage, contributing to the progress in material chemistry, coordination chemistry, and structural chemistry.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Physical

Modular design in metal-organic frameworks for oxygen evolution reaction

Jialong Ji et al.

Summary: Among cutting-edge materials for catalysis, metal-organic frameworks (MOFs) have gained popularity, particularly in the field of electrocatalysis. MOFs based on various transition metals have exhibited excellent performance, especially in the oxygen evolution reaction (OER), which is crucial for electrocatalysis. This study presents a new model design based on MOFs, which allows for the synthesis of various types of MOFs with specific properties by establishing proper connections between modules. The difficulties and potential of MOF-based catalysts for OER research are highlighted.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Analytical

Ni-B-Co nanoparticles based on ZIF-67 as efficient electrocatalyst for oxygen evolution reaction

Junxia Ding et al.

Summary: This study demonstrates the excellent OER activity and stability of a Co-based bimetallic boride electrocatalyst, named ZIF@Ni-B-Co. The catalyst shows a low overpotential and a better Tafel slope compared to the noble metal RuO2. The superior performance is attributed to the formation of metal-boron bond, specific morphology, large surface area, and fast charge transfer rate.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2022)

Article Green & Sustainable Science & Technology

Mo-induced in-situ architecture of NixCoyP/Co2P heterostructure nano-networks on nickel foam as bifunctional electrocatalysts for overall water splitting

Yuqi Zhang et al.

Summary: Transition metal phosphides (TMPs) are promising materials for water splitting due to their high electrical conductivity and stability. Doping and constructing heterostructure electrocatalysts can optimize the catalytic activity and efficiency of TMPs.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2022)

Article Chemistry, Physical

Electrocatalytic oxygen evolution reaction at IrOx supported by Ni/Co-ZIF-67: Controlled ratio of metallic Ir and Ir3+ states

Sakthivel Perumal et al.

Summary: Dispersion of ultrafine iridium oxide nanoparticles over nanosheet-shaped zeolitic imidazolate framework (ZIF) surface of bimetallic Ni/Co-ZIF-67 leads to superior oxygen evolution electrocatalysis performance. The optimized electrode assembly with high IrOx loading amount and evenly dispersed IrOx nanoparticles exhibits excellent catalytic parameters.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

Electronic and architecture engineering of hammer-shaped Ir-NiMoO4-ZIF for effective oxygen evolution

Ming Song et al.

Summary: Designing an electronic structure and architecture with appropriate binding strength and abundant active sites is crucial for boosting the oxygen evolution reaction (OER). In this study, a hammer-shaped structure was developed by in situ assembly of ZIF-67 nanocubes on the surface of one-dimensional NiMoO4 nanorods. The resulting NiMoO4-ZIF hammers showed high activity towards OER after doping with a low amount of Ir, delivering a high current density with a low overpotential.

CRYSTENGCOMM (2022)

Article Chemistry, Multidisciplinary

A two-dimensional zeolitic imidazolate framework loaded with an acrylate-substituted oxoiron cluster as an efficient electrocatalyst for the oxygen evolution reaction

Zhuojie Xiao et al.

Summary: In this study, a composite material ZIF-L@Fe-28, formed by loading 2D zelitic imidazolate frameworks (ZIF)-L with acrylate-substituted oxoiron cluster {Fe-28}, exhibited the best oxygen evolution reaction (OER) activity and stability. The superior performance was attributed to the bidirectional synergistic effect between {Fe-28} and ZIF, as well as the etching effect of {Fe-28} on ZIF-L in aqueous solution. These findings suggest that preparing ZIF composites loaded with OER-active metal sites may offer new opportunities for the design of novel non-noble electrocatalysts for OER.

NEW JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

Ir-Doped Co(OH)2 nanosheets as an efficient electrocatalyst for the oxygen evolution reaction

Yihao Gao et al.

Summary: Recently, Co-based metal-organic frameworks (Co-MOFs) have attracted significant research interest due to their large specific surface area, high porosity, tunable structure, and topological flexibility. However, the weak electrical conductivity and inferior stability of Co-MOFs greatly limit their application as electrocatalysts. In this study, ZIF-67 was grown on nickel foam using a room temperature soaking method, followed by assembly of Ir-Co(OH)(2)@ZIF-67/NF using a hydrothermal method. The prepared Ir-Co(OH)(2)@ZIF-67/NF nanosheets exhibited remarkable conductivity, larger electrochemical active surface area, and wider electron transport channels. The Ir-Co(OH)(2)@ZIF-67/NF required only ultralow overpotentials to reach certain current densities, with no obvious degradation observed for about 16 hours at a specific current density. This work offers a promising strategy for the development of high-performance MOF-derived materials as electrocatalysts for the oxygen evolution reaction under alkaline conditions.

DALTON TRANSACTIONS (2022)

Review Chemistry, Physical

Modified Metal-Organic Frameworks for Electrochemical Applications

Kefan Chen et al.

Summary: This review presents the characteristics and advantages of metal-organic frameworks (MOFs), as well as the synthesis, structure characterization, and electrochemical application of modified MOFs. Furthermore, it discusses the challenges and application prospects of modified MOFs in energy storage and conversion.

SMALL STRUCTURES (2022)

Review Chemistry, Multidisciplinary

Post-Synthetic Modification of Metal-Organic Frameworks Toward Applications

Sukhendu Mandal et al.

Summary: Post-synthetic modification (PSM) is a useful technique for preparing new MOFs with enhanced properties by modifying linkers and metal nodes. Widening applications of MOFs with compatible metals or ligands through PSM shows considerable potential for introducing desired properties and increasing structural stability.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Preparation of a Dual-MOF Heterostructure (ZIF@MIL) for Enhanced Oxygen Evolution Reaction Activity

Tao Zhao et al.

Summary: The study introduces a dual-MOF heterostructure with remarkable OER electrocatalytic performance, attributed to the exposed active sites, synergistic effect between ZIF-67 and MIL-100, and enhanced electron transfer ability.

CHEMISTRY-AN ASIAN JOURNAL (2021)

Article Chemistry, Applied

Continuous synthesis of ZIF-67 by a microchannel mixer: A recyclable approach

Meizhuo Zhang et al.

Summary: The microfluidic synthesis of a Zeolitic-Imidazole Framework ZIF-67 at ambient temperature and pressure with a high throughput and recycling ability has been reported. The mother liquor can be recycled multiple times in ethanol, but not in water solution. Control over the morphology and particle sizes of ZIF-67 can be achieved in a water-ethanol mixed solvent. Additionally, the influence of TEA on the ZIF-67 structure was investigated in detail.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Article Chemistry, Inorganic & Nuclear

Designed construction of hierarchical CoOOH@Co-FeOOH double-shelled arrays as superior water oxidation electrocatalyst

Enlai Hu et al.

Summary: In this study, hierarchical CoOOH@Co-FeOOH double-shelled arrays were synthesized, demonstrating superior activity towards the oxygen evolution reaction. The excellent performance can be attributed to the unique structural and compositional features, including remarkable electron transfer rate, robust structure, and abundant active sites.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Formation mechanism and properties of NiCoFeLDH@ZIF-67 composites

Huijie Zhou et al.

Summary: By growing NiCoFeLDH on the surface of ZIF-67, a multi-component hierarchical structure was obtained, significantly improving the capacitance performance of MOFs. Controlling the type and valence state of doped metals, as well as the reaction time, allows for effective control of the morphology transformation of MOF composites. This scheme is crucial for the design of MOF-based materials used in supercapacitor devices.

CHINESE CHEMICAL LETTERS (2021)

Article Chemistry, Multidisciplinary

Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction

Qingxin Zhang et al.

Summary: Developing large-scale electrocatalysts for the oxygen evolution reaction (OER) using molecular complexes is crucial. Electropolymerizing four cobalt porphyrins and corroles on electrode substrates in alkaline aqueous solutions resulted in Co-1-P@CC showing the highest activity with an onset overpotential of 380 mV. Long-term electrolysis tests confirmed the stability and effectiveness of these electropolymerized films as OER electrocatalysts.

CHINESE CHEMICAL LETTERS (2021)

Article Chemistry, Multidisciplinary

In Situ Thermal Solvent-Free Synthesis of Zeolitic Imidazolate Frameworks with High Crystallinity and Porosity for Effective Adsorption and Catalytic Applications

Jichao Wang et al.

Summary: The study developed a facile and eco-friendly method to synthesize zeolitic imidazole frameworks with high porosity through optimizing synthesis parameters, showing potential applications in adsorption and catalysis.

CRYSTAL GROWTH & DESIGN (2021)

Review Nanoscience & Nanotechnology

Design Engineering, Synthesis Protocols, and Energy Applications of MOF-Derived Electrocatalysts

Amr Radwan et al.

Summary: The significant progress of MOFs-derived electrocatalysts in ORR, OER, and HER applications is mainly attributed to their high-porosity structure, large surface area, and abundant active centers.

NANO-MICRO LETTERS (2021)

Article Chemistry, Physical

Borate Anion Dopant Inducing Oxygen Vacancies over Co3O4 Nanocages for Enhanced Oxygen Evolution

Xuetao Liu et al.

Summary: A sacrificial template strategy was used to prepare borate anion doped nanocages catalyst, which exhibited impressive OER performance with controllable morphology and oxygen vacancy defects, beneficial for accelerating electron transport rate and catalytic activity.

CATALYSTS (2021)

Article Chemistry, Physical

Porous metal-organic framework (MOF)-based and MOF-derived electrocatalytic materials for energy conversion

Kayode Adesina Adegoke et al.

Summary: Porous MOF-based and MOF-derived materials are ecofriendly and safe electrocatalysts that have gained attention for their exceptional compositions, diverse structures, and tunability. This study discusses the electrocatalytic performances of these materials for various energy conversion technologies and highlights the correlation between porous MOFs/MOF-derived structural parameters and electrocatalytic performance. Additionally, the study emphasizes the challenges, strategies, and prospects for advancing this field.

MATERIALS TODAY ENERGY (2021)

Review Chemistry, Multidisciplinary

ZIF-67-based catalysts for oxygen evolution reaction

Hui Wen et al.

Summary: The review discusses the application of imidazole zeolite framework (ZIF) and its derivatives in the oxygen evolution reaction (OER), emphasizing on the control of their morphology through doping and derivative composition engineering, as well as single-atom catalysis. The study also highlights the importance of understanding actual active sites through DFT calculations and proposes challenges and prospects for ZIF-67 based electrocatalysts.

NANOSCALE (2021)

Article Chemistry, Inorganic & Nuclear

Assembly of ZIF-67 nanoparticles and in situ grown Cu(OH)2 nanowires serves as an effective electrocatalyst for oxygen evolution

Lei Ye et al.

Summary: A self-supporting, binder-free electrocatalyst was successfully prepared in this study, exhibiting excellent performance and stability for the oxygen evolution reaction under alkaline conditions. This provides a feasible strategy for the rapid preparation of low-cost and efficient electrocatalysts in alkaline media.

DALTON TRANSACTIONS (2021)

Article Chemistry, Physical

Surface construction of loose Co(OH)2 shell derived from ZIF-67 nanocube for efficient oxygen evolution

Jun-Feng Qin et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

Article Nanoscience & Nanotechnology

Quasi-ZIF-67 for Boosted Oxygen Evolution Reaction Catalytic Activity via a Low Temperature Calcination

Rongmei Zhu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

Three-dimensional open CoMoOx/CoMoSx/CoSx nanobox electrocatalysts for efficient oxygen evolution reaction

Hui Xu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Chemistry, Multidisciplinary

Synthesis and Optimization of Zeolitic Imidazolate Frameworks for the Oxygen Evolution Reaction

Juntao Li et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Review Chemistry, Physical

Recent progress on metal-organic frameworks and their derived materials for electrocatalytic water splitting

Jing-Bo Tan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

Advanced framework-modified POM@ZIF-67 nanocomposites as enhanced oxygen evolution reaction electrocatalysts

Victor K. Abdelkader-Fernandez et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

Jiawei Wan et al.

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Physical

Oxygen Evolution Reaction Electrocatalytic Improvement in POM@ZIF Nanocomposites: A Bidirectional Synergistic Effect

Victor K. Abdelkader-Fernandez et al.

ACS APPLIED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Smart Yolk/Shell ZIF-67@POM Hybrids as Efficient Electrocatalysts for the Oxygen Evolution Reaction

Qin Yuan Li et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Materials Science, Multidisciplinary

Microwave-assisted synthesis and simultaneous electrochemical determination of dopamine and paracetamol using ZIF-67-modified electrode

Nguyen Thi Thanh Tu et al.

JOURNAL OF MATERIALS SCIENCE (2019)

Article Chemistry, Multidisciplinary

MXene Boosted CoNi-ZIF-67 as Highly Efficient Electrocatalysts for Oxygen Evolution

Yangyang Wen et al.

NANOMATERIALS (2019)

Article Multidisciplinary Sciences

Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide

Bryan H. R. Suryanto et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Inorganic & Nuclear

Core-shell-type ZIF-8@ZIF-67@POM hybrids as efficient electrocatalysts for the oxygen evolution reaction

Yan Wang et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

Article Chemistry, Physical

ZIF 67 Based Highly Active Electrocatalysts as Oxygen Electrodes in Water Electrolyzer

Shraboni Ghoshal et al.

ACS APPLIED ENERGY MATERIALS (2019)

Review Chemistry, Multidisciplinary

Metal-organic frameworks-based catalysts for electrochemical oxygen evolution

Qiurong Shi et al.

MATERIALS HORIZONS (2019)

Review Chemistry, Multidisciplinary

Innovative Strategies for Electrocatalytic Water Splitting

Bo You et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Multidisciplinary

Ultrathin Chiral Metal-Organic-Framework Nanosheets for Efficient Enantioselective Separation

Jun Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Engineering, Environmental

Polyoxometalate-based materials for advanced electrochemical energy conversion and storage

Qinyuan Li et al.

CHEMICAL ENGINEERING JOURNAL (2018)

Article Chemistry, Multidisciplinary

Spray drying of zeolitic imidazolate frameworks: investigation of crystal formation and properties

Somboon Chaemchuen et al.

CRYSTENGCOMM (2018)

Article Chemistry, Physical

Hollow POM@MOF hybrid-derived porous Co3O4/CoMoO4 nanocages for enhanced electrocatalytic water oxidation

Linjie Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Multidisciplinary

Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal-Organic Frameworks

Luis Garzon-Tovar et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Physical

Design Strategies toward Advanced MOF-Derived Electrocatalysts for Energy-Conversion Reactions

Jinlong Liu et al.

ADVANCED ENERGY MATERIALS (2017)

Article Materials Science, Multidisciplinary

Synthesis of Zn-BTC metal organic framework assisted by a home microwave oven and their unusual morphologies

Cleiser Thiago Pereira da Silva et al.

MATERIALS LETTERS (2016)

Article Chemistry, Multidisciplinary

Large-scale continuous hydrothermal production and activation of ZIF-8

A. S. Munn et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Physical

Effect of synthesis solvent on the breathing behavior of MIL-53(Al)

William P. Mounfield et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2015)

Article Chemistry, Multidisciplinary

Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent

Deborah Crawford et al.

CHEMICAL SCIENCE (2015)

Article Chemistry, Multidisciplinary

Polyoxometalate-Based Cobalt-Phosphate Molecular Catalysts for Visible Light-Driven Water Oxidation

Xin-Bao Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Inorganic & Nuclear

Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) in aqueous solution via microwave irradiation

Qilong Bao et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2013)

Article Chemistry, Multidisciplinary

Instant MOFs: continuous synthesis of metal-organic frameworks by rapid solvent mixing

Miquel Gimeno-Fabra et al.

CHEMICAL COMMUNICATIONS (2012)

Article Chemistry, Multidisciplinary

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal-Organic Framework

Tarun C. Narayan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Review Chemistry, Multidisciplinary

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks

Anh Phan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

Review Chemistry, Multidisciplinary

Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

Anne Dolbecq et al.

CHEMICAL REVIEWS (2010)

Review Thermodynamics

Recent progress in alkaline water electrolysis for hydrogen production and applications

Kai Zeng et al.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2010)

Review Chemistry, Multidisciplinary

Activating Pd by Morphology Tailoring for Oxygen Reduction

Li Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis

Helge Bux et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Applied

Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture

You-Kyong Seo et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2009)