4.7 Article

Dual-vapour-thermal engineering evoking bound water pathways of vanadium oxide for high-rate and durable zinc-ion storage

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 471, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.144739

Keywords

Vapour-thermal reconstruction; Bound water pathways; Oxygen-deficient structure; Vanadium oxide; Aqueous zinc-ion batteries

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Vanadium oxides were reconstructed as advanced cathode materials for AZIBs using a dual-vapour-thermal engineering strategy. The ethanol/water dual-vapour phase triggered the fast formation of oxygen-deficient vanadium oxide hydrates (VPH-VO) with rich bound water pathways, which shielded the electrostatic interaction within the lamellar [VOn] host and facilitated Zn2+ diffusion. The VPH-VO cathode showed outstanding capacity and high-rate cycling stability, making the dual-vapour-thermal engineering an efficient approach for high-performance AZIBs.
Vanadium oxides have attracted extensive attention as promising cathode materials for aqueous zinc-ion batteries (AZIBs) owing to their variable valences and laminar structures. However, the strong interaction between divalent Zn2+ and the [VOn] host lattice limits its application. In this study, a facile dual-vapour-thermal engineering strategy was proposed for the first time to reconstruct V2O5 as an advanced cathode for AZIBs. Synchrotron radiation X-ray adsorption and photoelectron spectroscopies revealed that the high pressure and thermal environments of the ethanol/water dual-vapour phase trigger the fast formation of oxygen-deficient vanadium oxide hydrates (VPH-VO) containing rich bound water pathways. The in situ Raman spectra verified that these bound water pathways shield the electrostatic interaction within the lamellar [VOn] host, providing a more favourable environment for Zn2+ diffusion. The VPH-VO cathode delivered an outstanding capacity of 452 mA h g-1 at 0.5 A/g and an excellent high-rate cycling stability of 242 mA h g-1 after 2000 cycles at 10 A/g. Density functional theory calculation disclosed the highly reversible Zn2+ adsorption/desorption and low zinc-ion migration barrier in the bound water pathways of VPH-VO. This pioneering dual-vapour-thermal engineering is an efficient fabrication approach for superior lamellar cathode materials for high-performance AZIBs.

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