Journal
CHEMICAL ENGINEERING JOURNAL
Volume 474, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.145666
Keywords
Topology; Multi-bond network; Multi-function; Lightweight-ultrastrong; Thermal insulation; Energy conservation
Categories
Ask authors/readers for more resources
By constructing a molecular topological structure in the composite system, the deep cross fusion of heterogeneous interfaces has been achieved in traditional inorganic composites, endowing them with unique properties such as lightweight ultrastrong, thermal insulation, shock absorption, and fire resistance.
The demand of thermal energy conservation and regulation using inorganic composites in green low-carbon modern society is urgent. However, the organic-inorganic heterogeneous interfacial compatibility in traditional inorganic composites mainly depends on the loose crystal layers via hydrogen bonding, which is prone to faults and the hole wall damaged under strong forces. Here, a molecular topological structure was constructed in the composites system. Our process includes generating dendritic molecular chains on bamboo fiber, activating crystals to increase active sites, and inducing the confined growth of crystals on bamboo fiber through the action of hydrogen bonding and electrostatic adsorption. A chitosan-acrylic acid graft copolymer (CS-g-PAA) was introduced, which responded to weak alkali environment, achieved multi-mode bonding effects such as dynamic hydrogen bond, ionic complex bond, enhanced covalent bond, metal coordination bond and polymer network. Therefore, achieving deep cross fusion of heterogeneous interfaces through this method endows topologically composites (TCS) with many unique properties such as lightweight ultrastrong, thermal insulation, shock absorption, and fire resistance. The TCS was 8 times stronger than traditional insulation materials, and the thermal conductivity (0.07-0.085 W.m(-1).k(-1)) was much lower than that of other inorganic insulation materials. This multifunctional TCS shows potential applications for building energy conservation, aerospace insulation, and aircraft arresting systems.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available