Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 22, Pages 4576-4578Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09598g
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Funding
- Natural Science Foundation (NSF) of China [21472153, 21332007]
- Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education
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The first enantioselective total synthesis of (+)-methoxystemofoline (2) and (+)-isomethoxystemofoline (3) has been reported. The synthesis employed the halide-assisted bromotropanonation method that we developed recently to construct the core structure, and Overman's strategy for the implementation of the butenolide moiety. Through this work, the structure of methoxystemofoline was revised as 2 with an E-alkene, and its absolute configuration was established.
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