Journal
CHEMICAL ENGINEERING JOURNAL
Volume 472, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.144870
Keywords
Gel polymer electrolyte; Agarose; Natural biopolymer; Solid-state; Zinc -air battery
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This research presents a novel gel polymer electrolyte (GPE) based on pure agarose from seaweed, serving as a smart alternative to liquid and gel electrolytes, with excellent physicochemical and electrochemical properties. The agarose gel with 2 wt% agarose and 8 M KOH electrolyte exhibits outstanding ionic conductivity, water retention, and zinc utilization in primary and secondary zinc-air batteries. It shows high round-trip efficiency and improved cyclability under different cycling conditions, making it a potential benchmark for future GPE-based zinc-air batteries.
Present Zn-air batteries (ZABs) are based on concentrated alkaline liquid electrolytes, with high ionic conductivity, but suffer from leakage, evaporation, and carbonate precipitation due to the semi-open characteristic of these systems. To overcome these issues, gel polymer electrolytes (GPEs), based on naturally occurring biopolymers, arise as a green option to overcome the above-mentioned limitations. In this work, a novel GPE based on pure agarose from seaweed is presented as a smart alternative to liquid (adsorbed on a separator) and gel electrolytes (based on synthetic polymers). The innovative synthesis method described can directly encapsulate concentrated KOH liquid electrolytes into an agarose matrix in one-pot; the process requiring approx. 10 min. The unique gel developed in this work, with 2 wt% agarose and 8 M KOH electrolyte, presents the best compromise between physicochemical and electrochemical properties, at lab scale. The characterization results revealed an outstanding ionic conductivity of 0.45 +/- 0.05 S cm(-1), approximate to 100% water retention up to 200-250 h, retarded Zn self-corrosion up to 30 days (symmetric cell under open circuit), average Zn utilization > 70-80% in primary ZABs in the range 1-20 mA cm(-2) with peaks of approximate to 96%. In secondary ZABs the gel electrolyte presents high round-trip efficiency and improved cyclability at high areal capacities, under soft and severe cycling conditions, never tested before. This agarose gel represents a potential benchmark for future development of GPEbased ZABs for stationary applications.
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