4.7 Article

Observation of aliphatic C-H•••X hydrogen bonds in imidazolium ionic liquids

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 15, Pages 3193-3195

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09783a

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Funding

  1. National Science Foundation [DUE-9952264, CHE-0845026]
  2. Comision Sectorial de Investigacion Cientifica [I+D 30/2012]

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Measurement of H/D isotope effects on the F-19 resonances of sequentially deuterated 1-n-butyl-3-methylimidazolium hexafluorophosphate and tetrafluoroborate isotopologues reveals the formation of aliphatic C-H center dot center dot center dot X hydrogen bonds between the fluorinated anions and protons along the N-alkyl sidechains of the cations.

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