Journal
CHEMICAL ENGINEERING JOURNAL
Volume 475, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.146098
Keywords
Molecular engineering; Aqueous zinc-ion batteries; MnO2; Intrinsic conductivity
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A molecular engineering strategy is proposed to enhance the electrical conductivity and reaction kinetics of manganese dioxide (MnO2). The modified MnO2 exhibits improved reaction kinetics and electrical conductivity, leading to high specific capacity and rate capability in zinc-ion batteries.
Manganese dioxide (MnO2) is a promising cathode for aqueous zinc-ion batteries (ZIBs) because of its low cost, high energy density and environmental friendliness. However, the intrinsic poor electrical conductivity and sluggish reaction kinetics lead to inferior rate capability, especially under high mass loading, which hinders its commercialization. Herein, we report a molecular engineering strategy that can enhance the intrinsic electrical/ ionic conductivity of MnO2 and accelerate reaction kinetics. Electrochemical analysis reveals that boron-modified MnO2 (B-MnO2) delivers improved reaction kinetics since the tailored boron atoms with lower electronegativity can abate the strong electrostatic interactions between the cations and cathode. Theoretical calculations demonstrate that B-MnO2 possesses a smaller bandgap than MnO2, which can enhance its electrical conductivity. As a result, the developed Zn/B-MnO2 batteries display a high specific capacity (325.3 mAh/g at 200 mA g-1) and remarkable rate capability (99.4 mAh/g at 10 A/g). More importantly, at high mass loadings of 25 and 30 mg cm-2, the B-MnO2 cathodes can still deliver high specific capacity of 197.2 and 176.5 mAh/g, respectively. This work will pave a way toward the commercial applications of Mn-based cathodes.
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