Journal
CERAMICS INTERNATIONAL
Volume 49, Issue 24, Pages 40275-40283Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2023.09.363
Keywords
MnZn ferrites; Rietveld refinement; Cation distribution; Molecular magnetic moment; Magnetic anisotropy
Categories
Ask authors/readers for more resources
This study investigates the effects of Cu substitution for Mn on the properties of MnZn ferrites. It is found that increasing Cu content enhances density, reduces porosity, and promotes grain growth. However, it also leads to reduced saturation magnetization and initial permeability, increased magnetic anisotropy, and deterioration of core loss.
While the Cu substitution in NiCuZn ferrites is known to enhance densification and increase the initial permeability (mu i), little is known about its effects in the MnZn based ferrites, which naturally possess a higher saturation magnetization (Ms) and mu i. In this study, the effects of Cu substitution for Mn on the power MnZn ferrites (Mn0.71xCuxZn0.22Fe2.07O4, x = 0.00-0.35) are investigated. With increasing Cu content, enhanced density, reduced porosity, and significant grain growth are observed. The cation distribution was determined using the Rietveld refinement, showing the strong tendency of Cu2+ ions to occupy the octahedral sites of the spinel lattice. The magnetization curves show reduced Ms with increasing Cu content. The magnetic anisotropy (|K|) was also determined from the magnetization curves using the law of approach to saturation and is seen to be increased by the increasing Cu content. The reduced Ms and increased |K| lead to the dramatic reduction of mu i from 2503 (x = 0.00) to 151 (x = 0.35) at room temperature. Despite the reduced Ms at room temperature, the Curie temperature (TC) is seen to increase with increasing Cu content from x = 0.05 to x = 0.35, indicating the relocation of cations at an elevated temperature. The cut-off frequency (fr) is increased with increasing Cu content, which corresponds to the reduced mu i. Moreover, the core loss (Pcv) of the MnCuZn ferrites was tested at 100kHz/200 mT, 200kHz/ 125 mT, and 300kHz/100 mT at room temperature, and is found to deteriorate with the increasing Cu content.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available