Journal
CERAMICS INTERNATIONAL
Volume 49, Issue 22, Pages 36743-36751Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2023.08.360
Keywords
Er2O3 anti-reflection films; CVD diamond; Oxygen/argon ratio; Microstructure; Optical properties
Categories
Ask authors/readers for more resources
Optical erbium oxide (Er2O3) films were prepared by RF magnetron sputtering to enhance the infrared transmittance of CVD diamond. The study analyzed the microstructure, composition, and optical properties of Er2O3 anti-reflection films with different oxygen/argon ratios. It was found that the surface roughness and crystalline structure of Er2O3 films decreased with an increase in the oxygen/argon ratio. The chemical composition of the films underwent a transformation, and defect behavior was observed at high oxygen/argon ratios. The highest transmittance was achieved at an oxygen/argon ratio of 1:35. A low oxygen/argon ratio was found to promote the growth and infrared transmittance of Er2O3 films.
Optical erbium oxide (Er2O3) films were prepared by radio frequency (RF) magnetron sputtering to improve the infrared (IR) transmittance of chemical vapor deposition (CVD) diamond. This study aims to analyze the microstructure, composition and optical properties of Er2O3 anti-reflection films at various oxygen/argon ratios. Atomic force microscopy (AFM) analysis was used to detect the surface morphology of chemical oxidation CVD diamond and Er2O3 films. The surface roughness of Er2O3 films decreased with an increase in the oxygen/argon ratio. The crystalline structure of Er2O3 films was analyzed by using X-ray diffraction. Meanwhile, a gradual decrease was observed when the crystallite size and its strain were calculated. This was due to the transformation of partial phases from monoclinic to cubic structures. The chemical composition of Er2O3 films was analyzed by X-ray photoelectron spectroscopy (XPS). The surface of Er2O3 films underwent a transformation from the un-stable structure of nonstoichiometric Er2O3-x to the stable structure of Er2O3 with an increase in the level of oxygen. Defect behavior was determined by transmission electron microscopy (TEM). Specifically, dislocation and twinning were observed at a high oxygen/argon ratio, which was mainly attributed to the competitive growth of polycrystalline Er2O3 films. The optical constants of Psi and Delta were shifted to lower wavelengths with increase oxygen/argon ratio. The maximum transmittance of the Er2O3/diamond film was 79% in the long-wavelength infrared (LWTR) range of 8-12 mu m at an oxygen/argon ratio of 1:35. This value was significantly higher than that of the high oxygen/argon ratio. The present study concludes that a low oxygen/argon ratio promotes the growth and IR transmittance of Er2O3 films.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available