Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5246-5249Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08598a
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Funding
- Spanish Ministerio de Economia y Competitividad [CTQ2013-43310-P]
- Generalitat Valenciana [PROMETEOII/2014/073]
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Japan Society for the Promotion of Science
- Universidad de Valencia
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The use of functionalised allylboronic esters in the catalytic enantio-selective allylboration of aldehydes is described for the first time. gamma-Silylallyl pinacolate derivatives give rise to alpha-silyl homoallylic alcohols in high yields, with complete diastereoselectivities and high enantio-selectivities, in most of the cases. The usefulness of such intermediates is showcased by their transformation into fluorinated allylic alcohols.
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