4.7 Article

Effect of ultra accurate control of electrolyte temperature on the performance of micro arc oxidation ceramic coatings

Journal

CERAMICS INTERNATIONAL
Volume 49, Issue 20, Pages 33236-33246

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2023.08.032

Keywords

Micro arc oxidation (MAO); Electrolyte temperature; Ceramic coating; Wear and corrosion resistance

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This article investigates the influence of electrolyte temperature on the performance of micro arc oxidation (MAO) ceramic coatings. It is found that there is a nonlinear correlation between electrolyte temperature and coating thickness and hardness. The corrosion and wear resistance of the coatings initially improve with increasing temperature but eventually deteriorate. At an electrolyte temperature of 40 degrees C, the coatings exhibit optimal corrosion and wear resistance.
The technique of micro arc oxidation (MAO) uses arc discharge and high-voltage breakdown to produce a ceramic layer on valve metal surfaces. However, the common method of MAO requires immersing the workpiece in an electrolyte solution, which can result in elevated temperatures due to the arc discharge, thus negatively affecting the coating's quality and performance. This article investigates the influence of electrolyte temperature on the performance of MAO ceramic coatings, with the assistance of a robotic arm enabling valve metal reaction without immersion in the electrolyte, and precise control of electrolyte temperature through a MAO temperature monitoring system. Various techniques, such as scanning electron microscopy (SEM), hardness testing, electrochemical corrosion experiments, and friction-wear experiments, were utilized to characterize the performance of the prepared coating. The results indicate a nonlinear correlation between the temperature of the electrolyte and the thickness and hardness of the ceramic coating. The corrosion and wear resistance of the MAO ceramic coatings initially improve with increasing electrolyte temperature but eventually deteriorate. At an electrolyte temperature of 40 degrees C, the MAO ceramic coating exhibits the optimal corrosion and wear resistance. The variation in electrolyte temperature affects the reactivity of the electrolyte ions, leading to changes in the morphology and properties of the resulting MAO ceramic coating. These findings offer valuable insights into the interaction mechanism between electrolyte temperature and the properties of the resulting MAO ceramic coating. This is of great significance in optimizing the MAO process for specific applications and improving the overall performance of ceramic coatings.

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