4.7 Article

Planar-chiral building blocks for metal-organic frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 23, Pages 4796-4798

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00694e

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Funding

  1. KIT
  2. Deutsche Forschungsgemeinschaft (DFG) (project B2) [SFB/TRR 88]
  3. Ataturk University Research Fund [2012/466]

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The first example of a planar-chiral building block being used for chiral metal-organic frameworks (MOFs) is presented. The porous MOF structure combined with the chiral properties of the planar linker allows a selective adsorption, demonstrated for a nonpolar terpene limonene in thin surface-mounted MOF films.

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