4.7 Article

9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 31, Pages 6734-6737

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10104a

Keywords

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Funding

  1. Green Photonics Project in NAIST
  2. MEXT
  3. Singapore MOE Tier 2 grant [MOE2014-T2-1-080]
  4. [22350083]
  5. [26105004]
  6. [26288038]
  7. Grants-in-Aid for Scientific Research [25620061, 25107519, 25288092, 26288038, 26600004, 26105004] Funding Source: KAKEN

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Stable 9,9'-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days.

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