Journal
CATALYSIS TODAY
Volume 420, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.cattod.2023.114081
Keywords
Nanoclusters; Microwave heating; Ag clusters; Grafting; Catalysis; Alkyne Cyclization
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Given the potential of metallic clusters, developing novel preparation methods to control cluster size accurately has become a research priority. Specifically, for catalytic applications, synthesizing and deploying metallic nanoclusters on a proper substrate is the main challenge. This study used an alternative reactor that combined ice cooling and microwave heating to synthesize Ag nanoclusters directly over a support with ordered mesopores. The method showed promising results in terms of catalytic activity and stability.
Given the exciting potential of metallic clusters in a variety of fields, the development of novel preparation methods to accurately controlling the cluster size has become a research priority. Specifically, for catalytic applications, the synthesis and deployment of metallic nanoclusters on a proper substrate is perhaps the main bottleneck. Here, we have adopted an alternative reactor that uses simultaneous ice cooling and microwave heating (unlike water ice is a low microwave absorber) for the synthesis of Ag nanoclusters directly over a support with ordered mesopores (SBA-15). The reactor design exploits the selectivity of microwave heating, assuring a rapid localized nucleation followed by a nearly instantaneous quenching that largely avoids the aggregation of nascent clusters as well as Ostwald ripening mechanisms. We have compared this new synthesis approach with some previously reported methods for the production of supported silver nanoclusters: conventional batch reactor and also a continuous flow microreactor. The resulting Ag clusters were initially analyzed in terms of size distribution, textural properties and catalytic activity in the reduction of 4-nitrophenol. Finally, encouraged by the good results obtained, these nanoclusters were also employed in the production of different cyclic organic compounds, building blocks for pharmaceutical and photochemical applications. The nanoclusters displayed a high catalytic activity, lowering the metal loading required to achieve high yield and selectivity. Furthermore, the stabilization of the clusters over the mesoporous substrate allowed their reuse in several reaction cycles. In fact, the method produced exceptionally stable Ag clusters, whose catalytic properties were preserved even after one year of storage.
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