Gas-phase epoxidation of Hexafluoropropene using molecular oxygen and alkali doped CuO catalyst: Mechanism and kinetics

The study investigated the partial oxidation of hexafluoropropene over CuO catalyst with molecular oxygen in a continuous flow fixed bed reactor. The catalysts were characterized using various techniques, and the results confirmed catalyst's structure-reactivity correlation. The major products were hexafluoropropene oxide (HFPO) and carbonyl fluoride, with minor trifluoroacetyl fluoride produced when the catalyst had significantly declined in primary activity. The maximum selectivity of 52.5% HFPO was obtained at 13.4% hexafluoropropene conversion at 4.5 bar and 453 K. The proposed redox mechanism kinetic model was in adequate agreement with the experimental data (R2 = 0.97 for COF2 and 0.67 for HFPO).

Automated summary

This study investigated the partial oxidation of hexafluoropropene over CuO catalyst using molecular oxygen. The catalysts were characterized, and the results confirmed the structure-reactivity correlation. The major products were hexafluoropropene oxide (HFPO) and carbonyl fluoride, with minor trifluoroacetyl fluoride produced when the catalyst had significantly declined in primary activity. The proposed redox mechanism kinetic model was in adequate agreement with the experimental data.