Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5486-5489Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09639h
Keywords
-
Categories
Funding
- Science and Industry Endowment Fund (SIEF)
- Australian Research Council [FT100100400, FT0991910]
- Australian Research Council [FT0991910, FT100100400] Funding Source: Australian Research Council
Ask authors/readers for more resources
For post-synthetic metallation (PSMet) of a metal-organic framework (MOF, [Mn-3(L-2)(L')] = 1) we show a solvent dependency for the form of the metallated product. PSMet of 1 with MnCl2 in ethanol leads to a single metal entity per coordinating site while acetonitrile yields a remarkably complex multiply metallated product; thus, determining the extent of metallation requires an intimate understanding of the chemistry occurring in the MOF pores.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available