Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 16, Pages 3363-3366Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08880h
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Funding
- DFG-CFN grant [A5.7]
- state of Baden-Wurttemberg
- Helmholtz association in the context of the STN program
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Photoreactive gold nanoparticles (NP) can be encoded in a spatially resolved fashion using direct laser writing techniques into variable patterns. The surface of the gold nanoparticles is imparted with photoreactivity by tethering photo-caged dienes ('photoenols'), which are able to undergo a rapid Diels-Alder cycloaddition with surface anchored enes. Subsequent to surface encoding, the particles feature residual caged dienes, which can be reactivated for secondary surface encoding.
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