☆ 4.7 Article

Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex

CHEMICAL COMMUNICATIONS (2015)

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Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 10, Pages 1897-1900

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07154a

Keywords

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Categories

Chemistry, Multidisciplinary

Funding

  1. Deutsche Forschungsgemeinschaft [SFB 623, GK 850]
  2. BMBF
  3. MWK-BW

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An efficient RhI-NHC-pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methyl-ketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by Lewis acids.

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