4.7 Article

Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5402-5405

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08718f

Keywords

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Funding

  1. EPSRC
  2. Royal Society
  3. University of Manchester
  4. European Commission Euratom FP7 [269923]
  5. EPSRC [EP/J002208/2, EP/G004846/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/G004846/1, EP/J002208/2] Funding Source: researchfish

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Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

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