4.7 Article

Electrodeposition of PbO and its in situ conversion to CH3NH3PbI3 for mesoscopic perovskite solar cells

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 8, Pages 1457-1460

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08269a

Keywords

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Funding

  1. National Natural Science Foundation of China [21174149, 51173190, 21073203, 21076002, 21121001]
  2. National 863 Program [2011AA050521]
  3. 973 Program [2009CB930404, 2011CB932303, 2011CB808400]
  4. Scientific Equipment Program, ACS [YZ201106]

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The perovskite CH3NH3PbI3 was prepared on a mesoscopic TiO2 film, starting from electrodepositing PbO, to iodination to PbI2, and then interdiffusion reaction with CH3NH3I. The as-prepared film was used as a light absorber for the perovskite solar cells, exhibiting a high PCE of 12.5% under standard AM 1.5 conditions.

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