4.7 Article

IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5271-5274

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08641d

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Funding

  1. CNRS
  2. University of Bari Aldo Moro
  3. Ministere de l'Enseignement Superieur et de la Recherche for a PhD fellowship

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Themesoionic 5-acetylimidazolium-4-olate serves as precursor for an anionic, hybrid NHC, IMes-acac'', consisting of fused diaminocarbene and acetylacetonato units, whose respective coordination abilities are evaluated by the formation of a series of representative copper(I) complexes illustrating the ambidentate character of the

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