4.7 Article

Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 4, Pages 703-706

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06719c

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Funding

  1. NWO (Netherlands Organisation for Scientific Research)
  2. Ministry of Education, Culture and Science [024.001.035]

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Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding alpha-substituted diarylmethylamines in excellent yields, through fast and clean reactions. Where it occurs, 1,2-reduction can be circumvented using readily accessible dialkylmagnesium reagents.

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