4.7 Article

Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H-H, B-H and C=C bonds with B(C6F5)(3) and boryl-borate lithium

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5505-5508

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07658c

Keywords

-

Funding

  1. Shanghai Science and Technology Committee [13QA1400500]
  2. Shanghai Leading Academic Discipline Project [B108]
  3. National Nature Science Foundation of China [21102018, 21273042, 21372048]
  4. National Basic Research Program of China [2011CB808505]

Ask authors/readers for more resources

The frustrated Lewis pair comprised of B(C6F5)(3) and a boryl-borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp(2) boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available