Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5505-5508Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07658c
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Funding
- Shanghai Science and Technology Committee [13QA1400500]
- Shanghai Leading Academic Discipline Project [B108]
- National Nature Science Foundation of China [21102018, 21273042, 21372048]
- National Basic Research Program of China [2011CB808505]
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The frustrated Lewis pair comprised of B(C6F5)(3) and a boryl-borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp(2) boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.
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