Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 15, Pages 3080-3082Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05626d
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Funding
- State of Mecklenburg-Vorpommern
- BMBF
- Alexander von Humboldt Foundation
- analytic department in Likat
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The first highly regioselective and general osmium-catalyzed hydroformylation of olefins to aldehydes is reported. The combination of Os-3(CO)(12) and imidazoyl-substituted phosphine ligands allows n-selective (up to 99%) hydroformylation of bulk aliphatic as well as functional alkenes in good yields (64-87%).
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