Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 11, Pages 2166-2169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08548e
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Funding
- Spanish Ministerio de Economia y Competitividad, Spain [MAT2011-24757]
- Materials Science PhD program of the Universitat Autonoma de Barcelona
- ConvEne IGERT Program [NSF-DGE 0801627]
- MRSEC Program of the NSF [DMR 1121053]
- ICREA Funding Source: Custom
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The new compounds LaSrSiO3N and LaBaSiO3N activated with Eu2+ are orange-red light-emitting luminescent materials under excitation in the UV-blue range. They represent the first examples of stoichiometric alkaline earth oxynitridosilicates with a beta-K2SO4 structure. The isostructural compound LaEuSiO3N is ferromagnetic with a Curie temperature of 3 K and also shows red luminescence (lambda(max) = 705 nm) under excitation at 405 nm.
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