Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 4, Pages 636-639Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06988a
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- NanoNextNL, a micro and nanotechnology consortium of the Government of the Netherlands
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A new class of redox active hydrogels composed of poly(ferrocenylsilane) polyanion and poly(ethylene glycol) chains was assembled, using a copper-free azide-alkyne Huisgen cycloaddition reaction. These organometallic hydrogels displayed reversible collapse and reswelling upon chemical oxidation and reduction, respectively, and formed relatively well-defined, unaggregated Pd(0) nanoparticles (8.2 +/- 2.2 nm) from K2PdCl4 salts.
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