4.7 Article

Anomalous self-reduction of layered double hydroxide (LDH): from α-Ni(OH)2 to hexagonal close packing (HCP) Ni/NiO by annealing without a reductant

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 6, Pages 1004-1007

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07767a

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Funding

  1. National Natural Science Foundation of China [51271169]
  2. National Science and Technology Support Program [2012BAK30B04]
  3. Key Science and Technology Innovation Team of Zhejiang Province [2010R50013]
  4. Program for Innovative Research Team in University of Ministry of Education of China [IRT13037]

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The traditional concept that nickel layered double hydroxide (Ni LDH, also known as alpha-Ni(OH)(2)) converts to NiO after annealing has been taken without doubt and utilized to fabricate NiO for years. This work reports that an anomalous self-reduction phenomenon can occur for Ni LDH synthesized from an ionic liquid system.

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